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    蔡云飞,男,1986年2月出生,重庆璧山人,理学博士。2017年10月以“百人计划”加入重庆大学化学化工学院,任特聘研究员、博士生导师。2009年本科毕业于四川大学化学学院,随后师从冯小明教授留校继续学习,并于2014年7月获得博士学位。同年获得德国洪堡学者奖学金,于2014年8月至2016年10月在德国亚琛工业大学从事博士后研究,2016年10月至2017年10月在沙特阿拉伯阿卜杜拉国王科技大学(KAUST)继续从事博士后研究,合作导师均为Magnus Rueping教授。主要从事有机合成方法学、药物化学、材料化学等方面的研究。主持国家自然科学基金青年项目、重庆市科委项目、重庆市人社局留创项目、重庆大学科研启动基金、中央高校经费。迄今已在 J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、ACS Catal.等国际知名期刊发表论文30余篇,其中多篇被Angew. Chem. Int. Ed.、Synfacts、Synform等作亮点评论,论文被引用1400余次,h-因子23。

联系方式

电话:15928708564

E-mail: yf.cai@cqu.edu.cn

通信地址:重庆市沙坪坝区大学城南路55号 重庆大学虎溪校区理科楼化学化工学院(邮编:401331)

研究方向

主要研究方向:有机合成新方法的开发及其在具有生理活性或药用价值分子合成中的应用。

主要研究内容:不对称催化与合成,可见光催化,纳米材料催化。欢迎有意向读硕、读博的同学报考。

代表性论文、专著和专利

 

1. Lei Xu, Sishi Zhong, Qian Yang, Jie Wei, Jiaming Zou, Hongxiang Li, and Yunfei Cai*. Catalytic Asymmetric Radical-Mediated Three-Component Piancatelli-Type Rearrangement of Furylalkenes. ACS Catal. 2021, 11, 1019810207.

2. Yali He, Xiao Dan, Yurong Tang,* Qian Yang, Wentao Wang,* and  Yunfei Cai*. Semi-heterogeneous photocatalytic fluoroalkylation-distal functionalization of unactivated alkenes with RFSO2Na under air atmosphere. Green Chem. 2021, 23, 95779582

3. Qian Yang, Guanglong Pan, Jie Wei, Wentao Wang, Yurong Tang,* and Yunfei Cai*. Remarkable Activity of Potassium-Modified Carbon Nitride for Heterogeneous Photocatalytic Decarboxylative Alkyl/Acyl Radical Addition and Reductive Dimerization of para-Quinone Methides. ACS Sustain. Chem. Eng. 2021, 9, 23672377.

4. Lei Xu, Hongxiang Li, Liuzhuang Xing, Qian Yang, Yurong Tang, and Yunfei Cai*. Retro-Aza-Piancatelli Rearrangement Triggered Cascade Reaction of Methyl Furylacrylates with Anilines to Access Cyclopenta[b]pyrrolidinones. J. Org. Chem. 2022, 87, 855865.

5. Guanglong Pan, Qian Yang, Wentao Wang, Yurong Tang,* and Yunfei Cai*. Heterogeneous Photocatalytic Cyanomethylarylation of Alkenes with Acetonitrile: Synthesis of Diverse Nitrogenous Heterocyclic Compounds. Beilstein J. Org. Chem. 2021, 17, 11711180.

6. Sishi Zhong, Lei Xu, and Yunfei Cai*. Recent Advances on Piancatelli Reactions and Related Cascade Processes. Synthesis 2022, 54, 589–599.

7. Lei Xu, Qian Yang, Shisi Zhong, Hongxiang Li, Yurong Tang,* and Yunfei Cai*. Ln(III)/Chiral Brønsted Acid Catalyzed Asymmetric Cascade Ring Opening/Aza-Piancatelli Rearrangement of D-A Cyclopropanes. Org. Lett. 2020, 22, 9016–9021.

8. Pengxin Geng, Yurong Tang, Guanglong Pan, Wentao Wang, Jinchuan Hu,* and Yunfei Cai*. A g-C3N4-based Heterogeneous Photocatalyst for Visible Light Mediated Aerobic Benzylic C-H Oxygenations. Green. Chem. 2019, 21, 6116–6122.

9. Yunfei Cai, Xiaohua Liu, Pengfei Zhou, and Xiaoming Feng*, Asymmetric Catalytic Halofunctionalization of α,β-Unsaturated Carbonyl Compounds. J. Org. Chem. 2019, 84, 1–13.

10. Yunfei Cai, Yurong Tang, Lulu Fan, Quntin Lefebvre, Hong Hou, Magnus Rueping*. Heterogeneous Visible-Light Photoredox Catalysis with Graphitic Carbon Nitride for α-Aminoalkyl Radical Additions, Allylations, and Heteroarylations. ACS Catal. 2018, 8, 9471−9476.

11. Yunfei Cai, Yurong Tang, Iuliana Atodiresei, and Magnus Rueping*, Catalytic AsymmetricPiancatelli Rearrangement: Brønsted Acid Catalyzed 4π Electrocyclization for the Synthesis of Multisubstituted Cyclopentenones. Angew. Chem. Int. Ed. 2016, 55, 14126–14130.

12. Yunfei Cai, Xiaohua Liu, Yonghai Hui, Jun Jiang, Wentao Wang, Weiliang Chen, Lili Lin, and Xiaoming Feng*, Catalytic Asymmetric Bromoamination of Chalcones: Highly Efficient Synthesis of Chiral α-Bromo-β-amino Ketone Derivatives. Angew. Chem. Int. Ed. 2010, 49, 6160–6164.

13. Yunfei Cai, Xiaohua Liu, Jun Jiang, Weiliang Chen, Lili Lin, and Xiaoming Feng*, Asymmetric Chloroamination Reaction of α,β-Unsaturated γ-Keto Esters and Chalcones, J. Am. Chem. Soc. 2011, 133, 5636–5639.

14. Yunfei Cai, Pengfei Zhou, Xiaohua Liu, Jiannan Zhao, Lili Lin, and Xiaoming Feng*, Diastereoselectively Switchable Asymmetric Haloaminocyclization for the Synthesis of Cyclic Sulfamates, Chem. Eur. J. 2015, 21, 6386–6389.

15. Yunfei Cai, Xiaohua Liu, Pengfei Zhou, Yulong Kuang, Lili Lin, and Xiaoming Feng*, Iron-Catalyzed Asymmetric Haloamination Reactions, Chem. Commun. 2013, 49, 8054–8056.

16. Yunfei Cai, Jun Li, Weiliang Chen, Mingsheng Xie, Xiaohua Liu, Lili Lin, and Xiaoming Feng*, Catalytic Asymmetric Sulfenylation of Unprotected 3-Substituted Oxindoles, Org. Lett. 2012, 14, 2726–2729.

17. Yunfei Cai, Xiaohua Liu, Jun Li, Wentao Wang, Weiliang Chen, Lili Lin, and Xiaoming Feng*, Asymmetric Iodoamination of Chalcones and 4-Aryl-4-oxobutenoates Catalyzed by a Complex Based on Scandium(III) and a N,N′-Dioxide Ligand, Chem. Eur. J. 2011, 17, 14916–14921.

18. Yunfei Cai, Wentao Wang, Ke Shen, Jun Wang, Xiaolei Hu, Lili Lin, Xiaohua Liu and Xiaoming Feng*, Highly enantioselective α-chlorination of cyclic β-ketoesters catalyzed by N,N’-Dioxide using NCS as the chlorine source, Chem. Commun. 2010, 46, 1250–1252.

 

团队仪器设备

高效液相色谱仪(自动进样、配系列手性色谱柱)、IKA旋转蒸发仪、IKA加热磁力搅拌器、管式马弗炉等。