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蓝宇，重庆大学化学化工学院教授，博士生导师，现任理论与计算化学重庆市重点实验室主任。 蓝宇教授在理论计算有机化学、金属有机化学等领域从事多年研究工作。提出了基于构建共价键和转化合成单元的机理分析方法，并应用于大量过渡金属催化和小分子催化偶联反应机理研究中，提出了一条全面系统的有机化学反应机理研究新模式。 蓝宇教授近5年来在J. Am. Chem. Soc.、Angew.、Nat. Commun.这三大期刊上以通讯作者发表论文27篇，目前总计在各学术刊物上发表论文160余篇，总引用次数已过4000次，目前15篇论文入选ESI高被引论文。蓝宇教授先后主持国家自然科学基金优秀青年基金项目1项、面上项目2项、青年项目1项。 蓝宇教授获2018年重庆市自然科学奖一等奖（第一完成人），获得“2016年中国化学会青年化学奖”。近三年在Acc. Chem. Res.、Chem. Soc. Rev.、Coor. Chem. Rev.等期刊以通讯作者受邀发表多篇综述。最近，Angew. Chem. Int. Ed. (IF = 12.1)在其Author Profile发表了蓝宇教授的作者简介。（Angew. Chem. Int. Ed. 2018, 57, 11852.） |
联系方式
(Email) lanyu@cqu.edu.cn
研究方向
1.自由基偶联反应相关机制；
2.电环化反应机理与选择性；
3.过渡金属促进烃类官能团化反应机理；
4.小分子催化反应立体化学。
代表性论文、专著和专利
(209) “Mechanistic studies on nickel-catalyzed enantioselective [3 + 2] annulation for γ-butenolide synthesis via C-C activation of diarylcyclopropenones” Bai, D.*; Liu, S.; Chen, J.; Yu, Y.; Wang, M.; Chang, J.; Lan, Y.*; Li, X.* Org. Chem. Front. 2021, 8, ASAP. (DOI: 10.1039/D1QO00322D)
(208) “Tuning the reactivity of alkoxyl radicals from 1,5-hydrogen atom transfer to 1,2-silyl transfer” Yang, Z.; Niu, Y.; He, X.; Chen, S.; Liu, S.; Li, Z.; Chen, X.; Zhang, Y.; Lan, Y.*; Shen, X.* Nat. Commun. 2021, 12, 2131. (DOI: 10.1038/s41467-021-22382-y)
(207) “Biomimetic Carbene Cascades Enabled Imine Derivative Migration from Carbene-Bearing Thiocarbamates” Li, X.; Chen, H.; Xuan, Q.; Ma, S.; Lan, Y.*; Song, Q.* Org. Lett. 2021, 23, 3518-3523. (DOI: 10.1021/acs.orglett.1c00930)
(206) “Oxidation of Pd(II) with disilane in a palladium-catalyzed disilylation of aryl halides: a theoretical view” Zhang, J.; Liu, S.; Zhang, T.; Liu, T.*; Lan, Y.* Dalton Trans. 2021, 49, ASAP. (DOI: 10.1039/d1dt00399b)
(205) “Metal-free C(sp3)–H functionalization of sulfonamides via strain-release rearrangement” Hu, J.*; Yang, X.; Shi, S.; Cheng, B.; Luo, X.*; Lan, Y.*; Loh, T.-P.* Chem. Sci. 2021, 12, 4034-4340. (DOI: 10.1039/d0sc06603f)
(204) “Theoretical Model for N‑Heterocyclic Carbene-Catalyzed Desymmetrizing [4 + 1] and [4 + 2] Annulations of an Enal and Aryldialdehyde with 1,3-Cyclopentenedione” Wang, X.; Li, S.-J.; Wang, Y.-N.; Wei, D.*; Lan, Y.* Org. Lett. 2021, 23, 2421-2425. (DOI: 10.1021/acs.orglett.1c00270)
(203) “Insights into the chiral sulfide/selenide-catalyzed electrophilic carbothiolation of alkynes: mechanism and origin of axial chirality” Zhang, Q.-Y.; Li, S.-J.; Wang, Y.; Song, J.; Lan, Y.*; Wei, D.* Org. Chem. Front. 2021, 8, 1983-1990. (DOI: 10.1039/d1qo00036e)
(202) “Ligand coordination- and dissociation induced divergent allylic alkylations using alkynes” Huang, Y.; Ma, C.; Liu, S.; Yang, L.-C.; Lan, Y.*; Zhao, Y.* Chem 2021, 7, 812-826. (DOI: 10.1016/j.chempr.2021.02.018)
(201) “On the mechanism of homogeneous Pt-catalysis: A theoretical view” Chen, H.; Li, Y.*; Liu, S.*; Xiong, Q.; Bai, R.; Wei, D.*; Lan, Y.* Coor. Chem. Rev. 2021, 437, 213863. (DOI: 10.1016/j.ccr.2021.213863)
(200) “Synergistic Dinuclear Rhodium Induced Rhodium-Walking Enabling Alkene Terminal Arylation: A Theoretical Study” Heng, D.; Chen, H.; He, X.; Liu, S.; Zhu, L.; Zhong, K.; Zhang, T.; Bai, R.*; Lan, Y.* ACS Catal. 2021, 11, 3975-3987. (DOI: 10.1021/acscatal.0c05554)
(199) “Desymmetrization of 1,3-Diones by Catalytic Enantioselective Condensation with Hydrazine” Yang, B.; Dai, J.; Luo, Y.; Lau, K. K.; Lan, Y.*; Shao, Z.*; Zhao, Y.* J. Am. Chem. Soc. 2021, 143, 4179-4186. (DOI: 10.1021/jacs.1c01366)
(198) “Multiple Functional Organocatalyst-Promoted Inert C–C Activation: Mechanism and Origin of Selectivities” Zhang, M.; Wang, Y.; Li, S.-J.; Wang, X.; Shi, Q.; Li, X.; Qu, L.-B.; Wei, D.*; Lan, Y.* ACS Catal. 2021, 11, 3443-3454. (DOI: 10.1021/acscatal.0c05511)
(197) “How Solvents Control the Chemoselectivity in Rh-Catalyzed Defluorinated [4 + 1] Annulation” Liu, S.; Zhu, L.; Zhang, T.; Zhong, K.; Li, S.-J.; Bai, R.*; Lan, Y.* Org. Lett. 2021, 23, 1489-1494. (DOI: 10.1021/acs.orglett.1c00223)
(196) “Catalytic Atroposelective Catellani Reaction Enables to Construct Axially Chiral Biaryl Monophosphine Oxides” Feng, Q.; Ma, X.; Bao, W.; Li, S.-J.; Lan, Y.*; Song, Q.* CCS Chem. 2021, 3, 377-387. (DOI: 10.31635/ccschem.021.202000725)
(195) “Aryne 1,2,3,5-Tetrasubstitution Enabled by 3‑Silylaryne and Allyl Sulfoxide via an Aromatic 1,3-Silyl Migration” Shi, J.; Li, L.; Shan, C.; Wang, J.; Chen, Z.; Gu, R.; He, J.; Tan, M.; Lan, Y.*; Li, Y.* J. Am. Chem. Soc. 2021, 143, 2178-2184. (DOI: 10.1021/jacs.0c11119)
(194) “Lewis acid–catalyzed domino generation/[2,3]-sigmatropic rearrangement of ammonium ylidesto access chiral azabicycles” Xi, S.; Dong, J.; Chen, H.; Dong, Q.; Yang, J.; Tan, Q.; Zhang, C.; Lan, Y.*; Zhang, M.* Sci. Adv. 2021, 7, eabd5290. (DOI: 10.1126/sciadv.abd5290)
(193) “Rhodium-Catalyzed Atroposelective Construction of Indoles via C-H Bond Activation” Sun, L.; Chen, H.; Liu, B.; Chang, J.; Kong, L.; Wang, F.*; Lan, Y.*; Li, X. Angew. Chem. Int. Ed. 2021, 60, 8391-8395. (DOI: 10.1002/anie.202012932)
(192) “Predicting the origin of selectivity in NHCcatalyzed ring opening of formylcyclopropane: a theoretical investigation” Wang, Y.; Qiao, Y.; Lan, Y.*; Wei, D.* Catal. Sci. Tech. 2021, 11, 332-337. (DOI: 10.1039/d0cy01768j)
(191) “Is the reaction sequence in phosphine-catalyzed [8+2] cycloaddition controlled by electrophilicity?” Lin, W.-X.; Pei, Z.; Gong, C.; Mo, H.; Yang, K.; Qu, L.-B.; Wei, D.; Song, J.-S.*; Li, S.-J.*; Lan, Y.* Chem. Commun. 2021, 57, 761-764. (DOI: 10.1039/d0cc07370a)
(190) “Mechanistic insights into the rhodium-copper cascade catalyzed dual C-H annulation of indoles” He, X.; Zhu, L.; Heng, D.; Liu, F.; Liu, S.; Zhong, K.; Shan, C.*; Bai, R.*; Lan, Y.* Org. Chem. Front. 2020, 7, 1739-1746. (DOI: 10.1039/D0QO01332C)
(189) “Elemental sulfur enabled divergent synthesis of disulfides, diselenides and polythiophenes from β-CF3-1,3-enynes” Jin, S.; Li, S.-J.; Ma, X.; Su, J.; Chen, H.; Lan, Y.*; Song, Q.* Angew. Chem. Int. Ed. 2021, 60, 881-888. (DOI: 10.1002/anie.202009194)
(188) “Possible Mechanisms and Origin of Selectivities for Phosphine-Catalyzed [2+n] (n=3, 4) Annulations of Saturated Amines and δ-Acetoxy Allenoates” Yang, T.-T.; Wang, C.; Li, S.-J.; Zhang, M.; Wei, D.*; Lan, Y.* Asian J. Org. Chem. 2021, 10, 619-625. (DOI: 10.1002/ajoc.202000679)
(187) “How to inverse the chemoselectivity of nucleophilic addition by using a Lewis acid/Brønsted base pair catalyst: A theoretical view” Liu, C.; Li, S.-J.; Han, P.; Qu, L.-B.*; Lan, Y.* J. Mol. Catal. A, Chemical 2021, 499, 111318. (DOI: 10.1016/j.mcat.2020.111318)
(186) “Manganese-Catalyzed Asymmetric Hydrogenation of Quinolines Enabled by π-π Interaction” Liu, C.; Wang, M.; Liu, S.; Wang, Y.; Peng, Y.; Lan, Y.*; Liu, Q.* Angew. Chem. Int. Ed. 2021, 60, 5108-5113. (DOI: 10.1002/anie.202013540)
(185) “Insight into Organocatalytic Arylation of Azonaphthalenes with α-Chloroaldehydes: General Mechanism and Origin of Selectivities” Wang, X.; Wang, Y.; Wei, D.*; Lan, Y.* Chem. Commun. 2021, 57, 219-222. (DOI: 10.1039/D0CC07260E)
(184) “N-Heterocyclic carbene-catalyzed enantioselective hetero-[10 +2] annulation” Peng, Q.; Li, S.-J.; Zhang, B.; Guo, D.; Lan, Y.*; Wang, J.* Commun. Chem. 2020, 3, 177. (DOI: 10.1038/s42004-020-00425-7)
(183) “Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst” Tang, B.-C.; Lin, W.-X.; Chen, X.-L.; He, C.; Ma, J.-T.; Wu, Y.-D.; Lan, Y.*; Wu, A.-X.* Nat. Commun. 2020, 11, 5662. (DOI: 10.1038/s41467-020-19508-z)
(182) “Iron-Catalyzed Radical Relay Enabling the Modular Synthesis of Fused Pyridines from Alkyne-Tethered Oximes and Alkenes” Du, F.; Li, S.-J.; Jiang, K.; Zeng, R.; Pan, X.-C.*; Lan, Y.*; Chen, Y.-C.*; Wei, Y.* Angew. Chem. Int. Ed. 2020, 59, 23755-23762. (DOI: 10.1002/anie.202010752)
(181) “Chemoselective Union of Olefins, Organohalides, and Redox-Active Esters Enables Regioselective Alkene Dialkylation” Yang, T.; Jiang, Y.; Luo, Y.; Li, J. J. H.; Lan, Y.*; Koh, M. J.* J. Am. Chem. Soc. 2020, 142, 21410-21419. (DOI: 10.1021/jacs.0c09922)
(180) “Nickel-Catalyzed C-F/N-H Annulation of Aromatic Amides with Alkynes: Activation of C-F Bonds under Mild Reaction Conditions” Nohira, I.; Liu, S.; Bai, R.; Lan, Y.*; Chatani, N.* J. Am. Chem. Soc. 2020, 142, 17306-17311. (DOI: 10.1021/jacs.0c08512)
(179) “Palladium-Catalyzed Intermolecular trans-Selective Carbofunctionalization of Internal Alkynes to Highly Functionalized Alkenes” Lv, W.; Liu, S.; Chen, Y.; Wen, S.; Lan, Y.*; Cheng, G.* ACS Catal. 2020, 10, 10516-10522. (DOI: 10.1021/acscatal.0c02522)
(178) “Hydrogen-Bonding-Promoted Cascade Rearrangement Involving the Enlargement of Two Rings: Efficient Access to Polycyclic Quinoline Derivatives” Cao, W.-B.; Li, S.; Xu, M.-M.; Li, H.; Xu, X.-P.*; Lan, Y.*; Ji, S.-J.* Angew. Chem. Int. Ed. 2020, 59, 21425-21430. (DOI: 10.1002/anie.202008110)
(177) “Visible Light-Driven Anti-Markovnikov Hydrocarboxylation of Acrylates and Styrenes with CO2” Huang, H.; Ye, J.-H.; Zhu, L.; Ran, C.-K.; Miao, M.; Wang, W.; Chen, H.; Zhou, W.-J.; Lan, Y.*, Yu, B.; Yu, D.-G.* CCS Chem. 2020, 2, 1746-1759. (DOI: 10.31635/ccschem.020.202000374)
(176) “Visible-Light Photoredox-Catalyzed Remote Difunctionalizing Carboxylation of Unactivated Alkenes with CO2” Song, L.; Fu, D.-M.; Chen, L.; Jiang, Y.-X.; Ye, J.-H.; Zhu, L.; Lan, Y.*; Fu, Q.; Yu, D.-G.* Angew. Chem. Int. Ed. 2020, 59, 21121-21128. (DOI: 10.1002/anie.202008630)
(175) “Utilizing Vinylcyclopropane Reactivity: Palladium-Catalyzed Asymmetric [5+2] Dipolar Cycloadditions” Li, M.-M.; Xiong, Q.; Qu, B.-L.; Xiao, Y.-Q.; Lan, Y.*; Lu, L.-Q.; Xiao, W.-J. Angew. Chem. Int. Ed. 2020, 59, 17429-17434. (DOI: 10.1002/anie.202006366)
(174) “Dynamic Kinetic Asymmetric Amination of Alcohols Assisted by Microwave: Stereo-convergent Access to Tetralin- and Indane-Derived Chiral Amines” Rong, Z.-Q.; Yu, Z.; Weng, C.; Yang, L.-C.; Lu, S.; Lan, Y.*; Zhao, Y.* ACS Catal. 2020, 10, 9464-9475. (DOI: 10.1021/acscatal.0c02468)
(173) “Cu-Catalyzed Regio- and Stereodivergent Chemoselective sp2/sp3 1,3- and 1,4-Diborylations of CF3-Containing 1,3-Enynes” Kuang, Z.; Chen, H.; Qiu, J.; Ou, Z.; Lan, Y.*; Song, Q.* Chem 2020, 6, 2347-2363. (DOI: 10.1016/j.chempr.2020.06.034)
(172) “Insights into Lewis base-catalyzed chemoselective [3 + 2] and [3 + 4] annulation reactions of MBH carbonates” Deng, Q.; Li, S.-J.; Wei, D.*; Lan, Y.* Org. Chem. Front. 2020, 7, 1828-1836. (DOI: 10.1039/d0qo00457j)
(171) “Mechanism and Regioselectivity of 1,3-Dipolar Cycloaddition of Nitrile Oxides to 3-Methylene Oxindole: A Density Functional Theory Study” Luo, X.; Liu, S.; Lan, Y.* ChemistrySelect 2020, 5, 8421-8428. (DOI: 10.1002/slct.202002672)
(170) “σ-Bond Migration Assisted Decarboxylative Activation of Vinylene Carbonate in Rh-Catalyzed 4+2 Annulation: A Theoretical Study” Shen, B.; Liu, S.; Zhu, L.; Zhong, K.; Liu, F.; Chen, H.; Bai, R.*; Lan, Y.* Organometallics 2020, 39, 2813-2819. (DOI: 10.1021/acs.organomet.0c00248)
(169) “Prediction of NHC-catalyzed chemoselective functionalizations of carbonyl compounds: A general mechanistic map” Li, X.; Xu, J.; Li, S.-J.; Qu, L.-B.; Li, Z.; Chi, Y. R.; Wei, D.*; Lan, Y.* Chem. Sci. 2020, 11, 7214-7225. (DOI: 10.1039/D0SC01793K)
(168) “Regio- and Enantioselective Palladium-Catalyzed Asymmetric Allylation of N-Fluorenyl Trifluoromethyl Imine” Wang, W.; Xiong, Q.; Gong, L.; Wang, Y.; Liu, J.*; Lan, Y.*; Zhang, X.* Org. Lett. 2020, 22, 5479-5485. (DOI: 10.1021/acs.orglett.0c01836)
(167) “Palladium-Catalyzed Asymmetric [8+2] Dipolar Cycloadditions of Vinyl Carbamates and Photogenerated Ketenes” Zhang, Q.-L.; Xiong, Q.; Li, M.-M.; Xiong, W.; Shi, B.; Lan, Y.*; Lu, L.-Q.*; Xiao, W.-J. Angew. Chem. Int. Ed. 2020, 59, 14096-14100. (DOI: 10.1002/anie.202005313)
(166) “Stereoselective Access to [5.5.0] and [4.4.1] Bicyclic Compounds through Pd-Catalysed Divergent Higher-Order Cycloadditions” Yang, L.-C.; Wang, Y.-N.; Liu, R.; Luo, Y.; Ng, X. Q.; Yang, B.; Rong, Z.-Q.; Lan Y.*; Shao, Z.; Zhao, Y.* Nat. Chem. 2020, 12, 860-868. (DOI: 10.1038/s41557-020-0503-7)
(165) “Mechanism of Palladium-Catalyzed Spiroannulation of Naphthols with Alkynes: A Density Functional Theory Study” Luo, X.; Zhong, K.; Lan, Y.* ChemCatChem 2020, 12, 3863-3869. (DOI: 10.1002/cctc.202000613)
(164) “C(sp3)-CF3 Reductive Elimination from a Five-Coordinate Neutral Copper(III) Complex” J. Am. Chem. Soc. 2020, 142, 9785–9791. (DOI: 10.1021/jacs.0c03304)
(163) “Unveiling the Chemo- and Stereoselectivities of NHC-Catalyzed Reactions of Aliphatic Ester with Aminochalcone” Wang, Y.; Qu, L.-B.; Wei, D.*; Lan, Y.* J. Org. Chem. 2020, 85, 8437-8446. (DOI: 10.1021/acs.joc.0c00769)
(162) “Is Cu(III) a necessary intermediate in Cu-mediated coupling reactions? A mechanistic point of view” Li, S.-J.; Lan, Y.* Chem. Commun. 2020, 56, 6609-6619. (DOI: 10.1039/d0cc01946a)
(161) “Reagent addition sequence and equivalent in N-heterocyclic carbene-catalyzed nonpolar inversion enable conversion from aldimine to benzoxazole” Li, X.; Liu, J.; Zhang, Q.-C.; Zhang, W.*; Lan, Y.* Int. J. Quantum Chem. 2020, e26249. (DOI: 10.1002/qua.26249)
(160) “Highly Regio- and Enantioselective Hydrogenation of Conjugated α-Substituted Dienoic Acids” Liu, X.; Liu, S.; Wang, Q.; Zhou, G.; Yao, L.; Ouyang, Q.; Jiang, R.*; Lan, Y.*; Chen, W.* Org. Lett. 2020, 22, 3149-3154. (DOI: 10.1021/acs.orglett.0c00915)
(159) “With metal or not? a computationally predicted rule for a dirhodium catalyst in [3+3] cycloadditions of triazole with thiirane” Li, S.-J.; Li, X.; Mo, H.; Qu, L.-B.; Wei, D.*; Lan, Y.* Chem. Commun. 2020, 56, 4732-4735. (DOI: 10.1039/d0cc01293a)
(158) “Kinetically Controlled Radical Addition/Elimination Cascade: From Alkynyl Aziridine to Fluorinated Allenes” Song, T.; Zhu, L.; Li, H.; Tung, C.-H.; Lan, Y.*; Xu, Z.* Org. Lett. 2020, 22, 2419-2424. (DOI: 10.1021/acs.orglett.0c00622)
(157) “Protecting-Group-Free Total Syntheses of (±)-Norascyronones A and B” Cao, T.; Zhu, L.; Lan, Y.*; Huang, J.*; Yang, Z.* Org. Lett. 2020, 22, 2517-2521 (DOI: 10.1021/acs.orglett.0c00212)
(156) “Mechanism of Ir-catalyzed hydrogenation: A theoretical view” Cui, C.-X.; Chen, H.; Li, S.-J.; Zhang, T.; Qu, L.-B.; Lan, Y.* Coor. Chem. Rev. 2020, 412, 213251. (DOI: 10.1016/j.ccr.2020.213251)
(155) “A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group” Zhan, M.; Ding, Z.; Du, S.; Chen, H.; Feng, C.; Xu, M.; Liu, Z.; Zhang, M.; Wu, C.; Lan, Y.*; Li, P.* Nat. Commun. 2020, 11, 792. (DOI: 10.1038/s41467-020-14592-7)
(154) “Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C−Si Bond Activation: A Theoretical Study” Liu, S.; Zhang, T.; Zhu, L.; Liu, F.; Bai, R.*; Lan, Y.* Org. Lett. 2020, 22, 2124-2128. (DOI: 10.1021/acs.orglett.9b04636)
(153) “Origin of Regio- and Stereoselectivity in the NHC-catalyzed Reaction of Alkyl Pyridinium with Aliphatic Enal” Wang, Y.; Qu, L.-B.; Lan, Y.*; Wei, D.* ChemCatChem 2020, 12, 1068-1074. (DOI: 10.1002/cctc.201901965)
(152) “Nucleophilicity versus Brønsted basicity controlled chemoselectivity: mechanistic insight into silver- or scandium-catalyzed diazo functionalization” Liu, F.; Zhu, L.; Zhang, T.; Zhong, K.; Xiong, Q.; Shen, B.; Liu, S.; Lan, Y.*; Bai, R.* ACS Catal. 2020, 10, 1256-1263. (DOI: 10.1021/acscatal.9b02040)
(151) “Reaction Scope and Mechanistic Insights of Nickel-Catalyzed Migratory Suzuki-Miyaura Cross-Coupling” Li, Y.; Luo, Y.; Peng, L.; Li, Y.; Zhao, B.; Wang, W.; Pang, H.; Deng, Y.; Bai, R.; Lan, Y.*; Yin, G.* Nat. Commun. 2020, 11, 147. (DOI: 10.1038/s41467-019-14016-1)
(150) “Mechanism and origin of diastereoselectivity of N-heterocyclic carbene-catalyzed cross-benzoin reaction: A DFT study” Wang, Y.; Lan, Y.* Chin. Chem. Lett. 2020, 31, 736-738. (DOI: 10.1016/j.cclet.2019.08.010)
(149) “Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp3)-H Bond Allylation” Zhang, J.; Liu, D.; Liu, S.; Ge, Y.; Lan, Y.*; Chen, Y.* iScience, 2020, 23, 100755. (DOI: 10.1016/j.isci.2019.100755)
(148) “Mechanism and Substituent Effects of Benzene Arylation via a Phenyl Cation Strategy: A Density Functional Theory Study” Li, X.; Sun, L.; Zhang, Q.; Li, S.; Wang, Y.; Wei, D.; Zhang, W.*; Lan, Y.* ChemCatChem 2019, 11, 5068-5076. (DOI: 10.1002/cctc.201901120)
(147) “Highly Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters via Functionalization of 1,3-Dienes with CO2” Chen, X.-W.; Zhu, L.; Gui, Y.-Y.; Jing, K.; Jiang, Y.-X.; Bo, Z.-Y.; Lan, Y.*, Li, J.; Yu, D.-G.* J. Am. Chem. Soc. 2019, 141, 18825-18835. (DOI: 10.1021/jacs.9b09721)
(146) “Unveiling How Intramolecular Stacking Modes of Covalently Linked Dimers Dictate Photoswitching Properties” Lu, R.-Q.; Yan, X.-Y.; Zhu, L.; Yang, L.-L.; Qu, H.; Wang, X.-C.*; Luo, M.; Wang, Y.; Chen, R.; Wang, X.-Y.; Lan, Y.*; Pei, J.; Weng, W.; Xia, H.; Cao, X.-Y.* Nat. Commun. 2019, 10, 5480. (DOI: 10.1038/s41467-019-13428-3)
(145) “Enantiodivergence by Minimal Modification of an Acyclic Chiral Secondary Aminocatalyst” Dai, J.; Wang, Z.; Deng, Y.; Zhu, L.; Peng, F.; Lan, Y.*; Shao, Z.* Nat. Commun. 2019, 10, 5182. (DOI: 10.1038/s41467-019-13183-5)
(144) “Oxidative Addition Promoted C−C Bond Cleavage in Rh-Mediated Cyclopropenone Activation: A DFT Study” Luo, Y.; Shan, C.; Liu, S.; Zhang, T.; Zhu, L.; Zhong, K.; Bai, R.*; Lan, Y.* ACS Catal. 2019, 9, 10876-10886. (DOI: 10.1021/acscatal.9b03361)
(143) “Unmasking the Ligand Effect in Manganese-Catalyzed Hydrogenations: Mechanistic Insight and Catalytic Application” Wang, Y.; Zhu, L.; Shao, Z.; Li, G.; Lan, Y.*; Liu, Q.* J. Am. Chem. Soc. 2019, 141, 17337-17349. (DOI: 10.1021/jacs.9b09038)
(142) “Origin of Regiochemical Control in Rh(III)/Rh(V)-Catalyzed Reactions of Unsaturated Oximes and Alkenes to Form Pyrdines” Li, Y.; Chen, H.; Qu, L.-B.; Houk, K. N.*; Lan, Y.* ACS Catal. 2019, 9, 7154-7165. (DOI: 10.1021/acscatal.9b02085)
(141) “On the mechanism of palladium-catalyzed unsaturated bond transformation: A review of theoretical studies” Xiong, Q.; Chen, H.; Zhang, T.; Shan, C.; Bai, R.*; Lan, Y.* Asian J. Org. Chem. 2019, 8, 1194-1206. (DOI: 10.1002/ajoc.201900314)
(140) “Mechanism of Rhodium Catalyzed Desymmetrization by Hydroacylation: A DFT Study” Luo, X.; Peng, J.; Liu, S.; Zhong, K.; Zhang, T.; Chen, R.; Lan, Y.* Sci. Sin. Chem. 2019, 49, 1094-1103. (DOI: 10.1360/SSC-2019-0051)
(139) “Inverse Electron-Demand, Pd-Catalyzed Asymmetric [4+2] Cycloadditions Enabled by Chiral P,S-Ligand and Hydrogen Bonding” Wang, Y.-N.; Xiong, Q.; Lu, L.-Q.*; Zhang, Q.-L.; Wang, Y.; Lan, Y.*; Xiao, W.-J.* Angew. Chem. Int. Ed. 2019, 58, 11013-11017. (DOI: 10.1002/anie.201905993)
(138) “Revealing the Reduction Process of Cu(II) by Sodium Bis(trimethylsilyl)amide” Yang, D.; Yi, H.; Chen, H.; Qi, X.; Lan, Y.*; Pao, C.-W.; Lee, J.-F.; Zhang, H.; Chen, Y.-H.; Lei, A.* Faraday Discuss. 2019, 220, 105-112. (DOI: 10.1039/C9FD00034H)
(137) “Hydrogen-bond-induced chiral axis construction: theoretical study of cinchonine-thiourea-catalyzed enantioselective intramolecular cycloaddition” Shan, C.; Zhang, T.; Xiong, Q.; Yan, H.*; Bai, R.*; Lan, Y.* Chem. Asian J. 2019, 14, 2731-2736. (DOI: 10.1002/asia.201900624)
(136) “Geometry, stability and aromaticity of β-diketiminate-coordinated alkaline-earth compounds” Li, Y.; Chen, H.; Qu, L.; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2019, 30, 2249-2253. (DOI: 10.1016/j.cclet.2019.06.001)
(135) “S8-Catalyzed Triple Cleavage of Bromodifluoro Compounds for the Assembly of N-containing Heterocycles” Deng, S.; Chen, H.; Ma, X.; Zhou, Y.; Yang, K.; Lan, Y.*; Song, Q.* Chem. Sci. 2019, 10, 6828-6833. (DOI: 10.1039/c9sc01333d)
(134) “Unravelling the Mechanism and Selectivity of the NHC-catalyzed Three-Membered Ring‐Opening/Fluorination of Epoxy Enals: A DFT Study” Wang, Y.; Qu, L.-B.; Lan, Y.*; Wei, D.* ChemCatChem 2019, 11, 2919-2925. (DOI: 10.1002/cctc.201900424)
(133) “Mechanism of Brønsted-Base-Mediated Borylation of Propynols: A DFT Study” Chen, H.; Zhang, T.; Shan, C.; Liu, S.; Song, Q.*; Bai, R.*; Lan, Y.* Org. Lett. 2019, 21, 4924-4928. (DOI: 10.1021/acs.orglett.9b01180)
(132) “Key Intermediate in Copper-Mediated Arene Trifluoromethylation [nBu4N][Cu(Ar)(CF3)3]: Synthesis, Characterization and C(sp2)-CF3 Reductive Elimination” Lu, Z.; Liu, H.; Liu, S.; Leng, X.; Lan, Y.*; Shen, Q.* Angew. Chem. Int. Ed. 2019, 58, 8510-8514. (DOI: 10.1002/anie.201904041)
(131) “Chemoselective asymmetric dearomative [3 + 2] cycloaddition reactions of purines with aminocyclopropanes” Hao, E.-J.; Fu, D.-D.; Wang, D.-C.; Zhang, T.; Qu, G.-R.; Li, G.-X.; Lan, Y.*; Guo, H.-M. Org. Chem. Front. 2019, 6, 863-867. (DOI: 10.1039/c9qo00039a)
(130) “Theoretical Study of the Addition of Cu–Carbenes to Acetylenes to Form Chiral Allenes” Zhong, K.; Shan, C.; Zhu, L.; Liu, S.; Zhang, T.; Liu, F.; Shen, B.; Lan, Y.*; Bai, R.* J. Am. Chem. Soc. 2019, 141, 5227-5280. (DOI: 10.1021/jacs.8b13055)
(129) “Enantioselective Synthesis of Biaryl Atropisomers via Pd‐Catalyzed C–H Olefination using Chiral Spiro Phosphoric Acid Ligands” Luo, J.; Zhang, T.; Wang, L.; Liao, G.; Yao, Q.-J.; Wu, Y.-J.; Zhan, B.-B.; Lan, Y.*; Lin, X.-F.*; Shi, B.-F.* Angew. Chem. Int. Ed. 2019, 58, 6708-6712. (DOI: 10.1002/anie.201902126)
(128) “Asymmetric Propargylic Radical Cyanation Enabled by Dual Organophotoredox and Copper Catalysis” Lu, F.-D.; Liu, D.; Zhu, L.; Lu, L.-Q.*; Yang, Q.; Zhou, Q.-Q.; Wei, Y.; Lan, Y.*; Xiao, W.-J.* J. Am. Chem. Soc. 2019, 141, 6167-6172. (DOI: 10.1021/jacs.9b02338)
(127) “Theoretical prediction on the reactivity of the Co-mediated intramolecular Pauson-Khand reaction for constructing bicyclo-skeletons in natural products” Zhu, L.; Wang, Z.; Liu, S.; Zhang, T.; Yang, Z.*; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2019, 30, 889-894. (DOI: 10.1016/j.cclet.2019.03.024)
(126) “Role of Alkaline-Earth Metal-Catalyst: A Theoretical Study of Pyridines Hydroboration” Li, Y.; Wu, M.; Chen, H.; Xu, D.; Qu, L.; Zhang, J.; Bai, R.*; Lan, Y.* Front. Chem. 2019, accepted. (DOI: 10.3389/fchem.2019.00149)
(125) “Chiral Phosphoric Acid Catalyzed Asymmetric C(sp3)–H Functionalization of Biomass-Derived 2,5-Dimethylfuran via Two Sequential Cope-Type Rearrangements” Xu, L.; Chen, H.; Liu, J.; Zhou, L.; Liu, Q.; Lan, Y.*; Xiao, J.* Org. Chem. Front. 2019, accepted. (DOI: 10.1039/C8QO01375F)
(124) “Frontier Molecular Orbital Adjusted C–H Cleavage and Oxidative Addition in Nickel Catalyzed Alkyl C–H Arylation: A Computational Study” Zhang, T.; Liu, S.; Zhu, L.; Liu, F.; Zhong, K.; Zhang, Y.; Bai, R.*; Lan, Y.* Commun. Chem. 2019, 2, 31. (DOI: 10.1038/s42004-019-0132-5)
(123) “Palladium-Catalyzed Enantioselective C–H Aminocarbonylation: Synthesis of Chiral Isoquinolinones” Han, H.; Zhang, T.; Yang, S.-D.; Lan, Y.*; Xia, J.-B.* Org. Lett. 2019, 21, 1749-1754. (DOI: 10.1021/acs.orglett.9b00315)
(122) “Theoretical Study of Ni-Catalyzed C−N Radical−Radical Cross-Coupling” Liu, S.; Qi, X.*; Bai, R.; Lan, Y.* J. Org. Chem. 2019, 84, 3321-3327. (DOI: 10.1021/acs.joc.8b03245)
(121) “Investigating the Mechanism of Palladium Catalyzed Radical Oxidative C(sp3)-H Carbonylation: A DFT Study” Xiong, Q.; Xu, D.; Shan, C.; Liu, S.; Luo, Y.; Liu, F.; Liu, S.; Lan, Y.*; Bai, R.* Chem. Asian J. 2019, 14, 655-661. (DOI: 10.1002/asia.201801862)
(120) “Formal Asymmetric Cycloaddition of Activated α,β-Unsaturated Ketones with α-Diazomethylphosphonate Mediated by a Chiral Silver SPINOL Phosphate Catalyst” Zheng, B.; Chen, H.; Zhu, L.; Hou, X.; Wang, Y.; Lan, Y.*; Peng, Y.* Org. Lett. 2019, 21, 593-597. (DOI: 10.1021/acs.orglett.8b03436)
(119) “Mechanistic Insight into Palladium-Catalyzed Carbocyclization-Functionalization of Bisallene: A Computational Study” Zhang, J.; Shan, C.; Lv, K.; Zhu, L.; Li, Y.; Liu, T.*; Lan, Y.* ChemCatChem 2019, 11, 1228-1237. (DOI: 10.1002/cctc.201801934)
(118) “Kinetic Resolution of Allylic Alcohol with Chiral BINOL-based Alkoxides: A Combination of Experimental and Theoretical Studies” Liu, Y.; Liu, S.; Li, D.; Zhang, N.; Peng, L.; Ao, J.; Eui, C.; Lan, Y.*; Yan, H. J. Am. Chem. Soc. 2019, 141, 1150-1159. (DOI: 10.1021/jacs.8b12796)
(117) “Computational Advances Aiding Mechanistic Understanding of Silver-Catalyzed Carbene/Nitrene/Silylene Transfer Reactions” Zhang, J.; Shan, C.; Zhang, T.; Liu, T.*; Song, J.*; Lan, Y.* Coor. Chem. Rev. 2019, 382, 69-84. (DOI: 10.1016/j.ccr.2018.12.009)
(116) “Well-Designed Phosphine–Urea Ligand for Highly Diastereo- and Enantioselective 1,3-Dipolar Cycloaddition of Methacrylonitrile: A Combined Experimental and Theoretical Study” Xiong, Y.; Du, Z.; Chen, H.; Yang, Z.; Tan, Q.; Zhang, C.; Zhu, L.; Lan, Y.*; Zhang, M.* J. Am. Chem. Soc. 2019, 141, 961-971. (DOI: 10.1021/jacs.8b10939)
(115) “Probing Enantioselectivity in Rhodium-Catalyzed Si-C Bond Cleavage to Construct Silicon-Stereocenter: A Theoretical Study” Yu, Z.; Zhang, T.; Bai, R.; Lan, Y.* Cata. Sci. Tech. 2019, 9, 646-651. (DOI: 10.1039/C8CY02261E)
(114) “On the Mechanism of Transition Metal-Catalyzed C-F Functionalization: Theoretical Advances” Li, Y.; Wang, Y.; Zhu, L.; Qu, L.; Lan, Y.* Chin. J. Org. Chem. 2019, 39, 38-46. (DOI: 10.6023/cjoc201810020)
(113) “Theoretical Advances of Transition Metals Mediated C―H Bonds Cleavage” Shan, C.*; Bai, R.; Lan, Y.* Acta Phys. -Chim. Sin. 2019, 35, ASAP. (DOI: 10.3866/PKU.WHXB201810052)
(112) “Gas molecule adsorption on twisted nanographene C96H36 derivative: A theoretical study” Cui, C.-X.*; Tian, Y.; Zhang, Y.-P.; Qu, L.-B.; Lan, Y.* Carbon 2019, 143, 385-390. (DOI: 10.1016/j.carbon.2018.11.030)
(111) “Benchmark Study of Popular Density Functionals for Calculating Binding Energies of Three-Center Two-Electron Bonds” Cui, C.-X.; Xu, D.; Ding, B.-W.; Qu, L.-B.; Zhang, Y.-P.*; Lan, Y.* J. Comput. Chem. 2019, 40, 657-670. (DOI: 10.1002/jcc.25752)
(110) “Photoredox Catalysis Modulated Nickel-Catalyzed Divergent Difunctionalization of Ethylene” Li, J.; Luo, Y.; Cheo, H. W.; Lan, Y.*; Wu, J.* Chem 2019, 5, 192-203. (DOI: 10.1016/j.chempr.2018.10.006)
(109) “Mechanistic Insights into Manganese(I)-Catalyzed Chemoselective Hydroarylations of Alkynes: A Theoretical Study” Wang, Z.; Zhu, L.; Zhong, K.; Qu, L.-B.; Bai, R.*; Lan, Y.* ChemCatChem 2018, 10, 5820-5826. (DOI: 10.1002/cctc.201801301)
(108) “Retro-metal-ene versus retro-Aldol: Mechanistic insight into Rh-catalysed formal [3+2] cycloaddition” Liu, S.; Zhang, T.; Zhu, L.; Zhong, K.; Gong, J.; Yang, Z.*; Bai, R.*; Lan, Y.* Chem. Commun. 2018, 13551-13554. (DOI: 10.1039/C8CC08335E)
(107) “Difluoromethylated Organogold(III) Complex cis-[Au(PCy3)(4-F-C6H4)(CF2H)(Cl)]: Preparation, Characterization and its C(sp2)−CF2H Reductive Elimination” Liu, S.; Kang, K.; Liu, S.; Wang, D.; Wei, P.*; Lan, Y.*; Shen, Q. Organometallics 2018, 36, 3901-3908. (DOI: 10.1021/acs.organomet.8b00579)
(106) “Long Distance Unconjugated Agostic-Assisted 1,5-H Shift in a Rumediated Alder-Ene Type Reaction: Mechanism and Stereoselectivity” Shan, C.; Zhong, K.; Qi, X.; Xu, D.; Qu, L.-B.; Bai, R.*; Lan, Y.* Org. Chem. Front. 2018, 4, 3178-3185. (DOI: 10.1039/C8QO00699G)
(105) “Base-catalyzed Borylation/B-O Elimination of Propynols and B2pin2 Delivering Tetrasubstituted Alkenylboronates” Kuang, Z.; Chen, H.; Yan, J.; Yang, K.; Lan, Y.*; Song, Q.* Org. Lett. 2018, 29, 5153-5157. (DOI: 10.1021/acs.orglett.8b02077)
(104) “Mechanistic View of Ru-Catalyzed C–H Bond Activation and Functionalization: Computational Advances” Shan, C.; Zhu, L.; Qu, L.-B.; Bai, R.*; Lan, Y.* Chem. Soc. Rev. 2018, 47, 7552-7576. (DOI: 10.1039/c8cs00036k)
(103) “Toward a Predictive Understandings of Phosphine-Catalyzed [3+2] Annulation of Allenoates with Acrylate or Imine” Yu, Z.; Jin, Z.; Duan, M.; Bai, R.*; Lu, Y.*; Lan, Y.* J. Org. Chem. 2018, 83, 9729-9740. (DOI: 10.1021/acs.joc.8b01259)
(102) “One-pot synthesis of β-lactams by the Ugi and Michael addition cascade reaction” Gao, X.; Shan, C.; Chen, Z.; Liu, Y.; Zhao, X.; Zhang, A.; Yu, P.; Galons, H.*; Lan, Y.*; Lu, K.* Org. Biomol. Chem. 2018, 16, 6096-6105. (DOI: 10.1039/c8ob01176a)
(101) “Editorial: Introduction to the special column on organocatalysis” Lan, Y.*; Liu, X.* Chin. Chem. Lett. 2018, 29, 1179-1180. (DOI: 10.1016/j.cclet.2018.07.009)
(100) “Experimental and Theoretical Studies on Ru(II)-Catalyzed Oxidative C−H/C−H Coupling of Phenols with Aromatic Amides Using Air as Oxidant: Scope, Synthetic Applications and Mechanistic Insights” Zhang, L.; Zhu, L.; Zhang, Y.; Yang, Y.; Wu, Y.; Ma, W.; Lan, Y.*; You, J.* ACS Catal. 2018, 8, 8324-8335. (DOI: 10.1021/acscatal.8b02816)
(99) “C6-Selective Direct Arylation of 2-Phenylpyridine via an Activated N-methylpyridinium Salt: A Combined Experimental and Theoretical Study” Yin, C.; Zhong, K.; Li, W.; Yang, X.; Sun, R.; Zhang, C.; Zheng, X.; Yuan, M.; Li, R.; Lan, Y.*; Fu, H.*; Chen, H.* Adv. Synth. Catal. 2018, 360, 3990-3998. (DOI: 10.1002/adsc.201800666)
(98) “Mechanism investigation for anoin-assisted nickel catalyzed C–F bond functionalization reaction: a DFT study” Zeng, Z.; Zhang, T.; Yue, X.; Zhang, H.*; Bai, R.*; Lan, Y.* Sci. Sin. Chem. 2018, 48, 736-742. (DOI: 10.1360/N032018-00105)
(97) “Catalytic Lactonization of Unactivated Aryl C−H Bonds with CO2: Experimental and Computational Investigation” Song, L.; Zhu, L.; Zhang, Z.; Ye, J.-H.; Yan, S.-S.; Han, J.-L.; Yin, Z.-B.; Lan, Y.*; Yu, D.-G.* Org. Lett. 2018, 20, 3776-3779.(DOI: 10.1021/acs.orglett.8b01363)
(96) “Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions” Li, Y.; Cheng, Y.; Shan, C.; Zhang, J.; Xu, D.; Bai, R.; Qu, L.; Lan, Y.* Chin. J. Org. Chem. 2018, 38, 1885-1896. (DOI: 10.6023/cjoc201804031)
(95) “Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2” Yan, S.-S.; Zhu, L.; Ye, J.-H.; Zhang, Z.; Huang, H.; Zeng, H.; Li, C.-J.*; Lan, Y.*; Yu, D.-G.* Chem. Sci. 2018, 9, 4873-4878. (DOI: 10.1039/c8sc01299g)
(94) “Author Profile” Lan, Yu* Angew. Chem. Int. Ed. 2018, 57, 11852. (DOI: 10.1002/anie.201804435)
(93) “Redox-Neutral Access to Isoquinolinones via Rhodium(III)-Catalyzed Annulations of O‑Pivaloyl Oximes with Ketenes” Yang, X.; Liu, S.; Yu, S.; Kong, L.; Lan, Y.*; Li, X.* Org. Lett. 2018, 20, 2698-2701. (DOI: 10.1021/acs.orglett.8b00906)
(92) “Ruthenium(II)-enabled para-selective C–H difluoromethylation of anilides and their derivatives” Yuan, C.; Zhu, L.; Chen, C.; Chen, X.; Yang, Y.; Lan, Y.*; Zhao, Y.* Nat. Commun. 2018, 9, 1189. (DOI: 10.1038/s41467-018-03341-6)
(91) “Aryne Trifunctionalization Enabled by 3-Silylaryne as 1,2-Benzdiyne Equivalent” Lv, C.; Wan, C.; Liu, S.; Lan, Y.*; Li, Y.* Org. Lett. 2018, 20, 1919-1923. (DOI: 10.1021/acs.orglett.8b00469)
(90) “Counterion Effect and Directing Group Effect in Rh-Mediated C-H Bond Activation Processes: A Theoretical Study” Luo, Y.; Liu, S.; Xu, D.; Qu, L.-B.; Luo, X.*; Bai, R.*; Lan, Y.* J. Organomet. Chem. 2018, 862, 148-153. (DOI: 10.1016/j.jorganchem.2018.03.016)
(89) “Mechanistic Insight Into Cobalt-Catalyzed Stereodivergent Semihydrogenation of Alkynes: The Story of Selectivity Control” Qi, X.; Liu, X.; Qu, L.-B.; Liu, Q.*; Lan, Y.* J. Catal. 2018, 362, 25-34. (DOI: 10.1016/j.jcat.2018.03.016)
(88) “Theoretical insight into phosphoric acid-catalyzed asymmetric conjugate addition of indolizines to α,β-unsaturated ketones” Chen, H.; Zhu, L.; Zhong, K.; Yue, X.; Qu, L.-B.; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2018, 29, 1237-1241. (DOI: 10.1016/j.cclet.2018.03.018)
(87) “Mechanism of phosphinecatalyzed allene coupling reactions: advances in theoretical investigations” Cui, C.-X.; Shan, C.; Zhang, Y.-P.; Chen, X.-L.; Qu, L.-B.*; Lan, Y.* Chem. Asian J. 2018, 13, 1076-1088. (DOI: 10.1002/asia.201800146)
(86) “Ni-Catalyzed C–F Bond Functionalization of Unactivated Aryl Fluorides and Corresponding Coupling with Oxazoles” Yin, Y.; Yue, X.; Zhong, Q.; Jiang, H.; Bai, R.*; Lan, Y.*; Zhang, H. Adv. Synth. Catal. 2018, 360, 1639-1643. (DOI: 10.1002/adsc.201701506)
(85) “C–H bond Cleavage Occurring on a Rh(V) Intermediate: a Theoretical Study of Rh-Catalyzed Arene Azidation” Liu, S.; Qi, X.; Qu, L.-B.; Bai, R.*; Lan, Y.* Catal. Sci. Tech. 2018, 8, 1645-1651. (DOI: 10.1039/c7cy02367g)
(84) “Regioselective Palladium-Catalyzed C‑H Bond Trifluoroethylation of Indoles: Exploration and Mechanistic Insight” Zhang, H.; Wang, H.-Y.; Luo, Y.; Chen, C.; Cao, Y.; Chen, P.; Guo, Y.-L.; Lan, Y.*; Liu, G.* ACS Catal. 2018, 8, 2173-2180. (DOI: 10.1021/acscatal.7b03220)
(83) “Palladium-Catalyzed Intermolecular Ditrifluoromethoxylation of Unactivated Alkenes: CF3O- Palladation Initiated by Pd(IV)” Chen, C.; Luo, Y.; Fu, L.; Chen, P.; Lan, Y.*; Liu, G.* J. Am. Chem. Soc. 2018, 140, 1207-1210. (DOI: 10.1021/jacs.7b11470)
(82) “Insights of Disilylation and Distannation: Sequence Influence and Ligand/Steric Effect in Pd-Catalyzed Difunctionalization of Carbenes” Yue, X.; Shan, C.; Qi, X.; Luo, X.; Zhu, L.; Zhang, T.; Li, Y.; Li, Y.; Bai, R.*; Lan, Y.* Dalton Trans. 2018, 46, 1819-1826. (DOI: 10.1039/C7DT04084A)
(81) “Ruthenium(II)-catalyzed C-H Difluoromethylation of Ketoxime: Tuning the Regioselectivity from meta to para Position” Yuan, C.; Zhu, L.; Zeng, R.; Lan, Y.*; Zhao, Y.* Angew. Chem. Int. Ed. 2018, 57, 1277-1281. (DOI: 10.1002/anie.201711221)
(80) “On the Mechanism of Copper-Catalyzed Oxytrifluoromethylation of Allylamines with CO2: A Computational Study” Zhu, L.; Ye, J.-H.; Duan, M.; Qi, X.; Yu, D.-G.*; Bai, R.*; Lan, Y.* Org. Chem. Front. 2018, 4, 633-639. (DOI: 10.1039/C7QO00838D)
(79) “Ni(I)–Ni(III) vs Ni(II)–Ni(IV): Mechanistic Study of Ni-catalyzed Alkylation of Benzamides with Alkyl Halides” Li, Y.; Zou, L.; Bai, R.*; Lan, Y.* Org. Chem. Front. 2018, 4, 615-622. (DOI: 10.1039/C7QO00850C)
(78) “C(sp2)-C(sp2) Reductive Elimination from Well-Defined Diarylgold(III) Complexes” Kang, K.; Liu, S.; Xu, T.; Wang, D.; Leng, X.; Bai, R.; Lan, Y.*; Shen, Q.* Organometallics 2017, 35, 4727-4740. (DOI: 10.1021/acs.organomet.7b00588)
(77) “Reactivity and regioselectivity in Diels–Alder reactions of anion encapsulated fullerenes” Cui, C.-X.; Zhang, Z.-P.; Zhu, L.; Qu, L.-B.; Zhang, Y.-P.; Lan, Y.* Phys. Chem. Chem. Phys. 2017, 42, 30393-30401. (DOI: 10.1039/C7CP06365B)
(76) “Mechanism of Rhodium-Catalyzed C−H Functionalization: Advances in Theoretical Investigation” Qi, X.; Li, Y.; Bai, R.; Lan, Y.* Acc. Chem. Res. 2017, 50, 2799-2808. (DOI: 10.1021/acs.accounts.7b00400)
(75) “Radical Trifluoromethylative Dearomatization of Indoles and Furans with CO2” Ye. J.-H.; Zhu, L.; Yan, S.-S.; Miao, M.; Zhang, X.-C.; Zhou, W.-J.; Li, J.; Lan, Y.*; Yu, D.-G.* ACS Catal. 2017, 7, 8324-8330. (DOI: 10.1021/acscatal.7b02533)
(74) “Rhodium/Copper Cocatalyzed Highly trans-Selective 1,2- Diheteroarylation of Alkynes with Azoles via C−H Addition/Oxidative Cross-Coupling: A Combined Experimental and Theoretical Study” Tan, G.; Zhu, L.; Liao, X.; Lan, Y.*; You, J.* J. Am. Chem. Soc. 2017, 139, 15724-15737. (DOI: 10.1021/jacs.7b07242)
(73) “Nine-Membered Benzofuran-Fused Heterocycles: Enantioselective Synthesis by Pd-Catalysis and Rearrangement via Transannular Bond Formation” Rong, Z.-Q.; Yang, L.-C.; Liu, S.; Yu, Z.; Wang, Y.-N.; Tan, Z. Y.; Huang, R.-Z.; Lan, Y.*; Zhao, Y.* J. Am. Chem. Soc. 2017, 139, 15304-15307. (DOI: 10.1021/jacs.7b09161)
(72) “Mechanistic Study on the Fluoride-induced Activation of Kobayashi Precursor: pseudo-SN2 Pathway via a PentaCoordinated Silicon ate-Complex” Liu, S.; Li, Y.*; Lan, Y.* Eur. J. Org. Chem. 2017, 42, 6349-6353. (DOI: 10.1002/ejoc.201701249)
(71) “Cp*CoIII-Catalyzed Branch-Selective Hydroarylation of Alkynes via C−H Activation: Efficient Access to α-gem-Vinylindoles” Zhou, X.; Luo, Y.; Kong, L.; Xu, Y.; Zheng, G.; Lan, Y.*; Li, X.* ACS Catal. 2017, 7, 7296-7304. (DOI: 10.1021/acscatal.7b02248)
(70) “Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study” Xu, D.; Shan, C.; Li, Y.; Qi, X.; Luo, X.*; Bai, R.*; Lan, Y.* Inorg. Chem. Front. 2017, 4, 1813. (DOI: 10.1039/c7qi00459a)
(69) “From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3+2] Cycloaddition” Duan, M.; Zhu, L.; Qi, X.; Yu, Z.; Li, Y.; Bai, R.*; Lan, Y.* Sci. Rep. 2017, 7, 7619. ( DOI:10.1038/s41598-017-07863-9)
(68) “Catalyst-controlled regioselectivity in phosphine catalysis: the synthesis of spirocyclic benzofuranones via regiodivergent [3+2] annulations of aurones and an allenoate” Ni, H.; Yu, Z.; Yao, W.; Lan, Y.*; Ullah, N.*; Lu, Y.* Chem. Sci. 2017, 8, 5699-5704. (DOI: 10.1039/c7sc02176c)
(67) “Mechanistic insights into copper-catalyzed trifluoromethylation of aryl boronic acids: a theretical study.” He, X.; Shan, C.; Qi, X.*; Bai, R.*; Lan, Y.* Sci. Sin. Chem. 2017, 47, 859-864. (DOI: 10.1360/N032017-00056)
(66) “Ir(III)/Ir(V) or Ir(I)/Ir(III) Catalytic Cycle? Steric-Effect-Controlled Mechanism for the para-C−H Borylation of Arenes” Zhu, L.; Qi, X.; Li, Y.; Duan, M.; Zou, L.; Bai, R.*; Lan, Y.* Organometallics 2017, 36, 2107-2115. (DOI: 10.1021/acs.organomet.7b00151)
(65) “Chiral phosphine-mediated intramolecular [3+2] annulation: enhanced enantioselectivity by achiral Brønsted acid” Yao, W.; Yu, Z.; Wen, S.; Ni, H.; Ullah, N.*; Lan, Y.*; Lu, Y.* Chem. Sci. 2017, 8, 5196-5200. (DOI: 10.1039/c7sc00952f)
(64) “Enantioselective alkynylation of N-sulfonyl a-ketiminoesters via a Friedel–Crafts alkylation strategy” Liu, R.-R.; Zhu, L.; Hu, J.-P.; Lu, C.-J.; Gao, J.-R.; Lan, Y.*; Jia, Y.-X.* Chem. Commun. 2017, 52, 5890-5893. (DOI: 10.1039/c7cc01015j)
(63) “Bioinspired Total Synthesis of Homodimericin A” Huang, J.; Gu, Y.; Guo, K.; Zhu, L.; Lan, Y.*; Gong, J.*; Yang, Z.* Angew. Chem. Int. Ed. 2017, 56, 7890-7894. ( DOI: 10.1002/anie.201702768)
(62) “Mechanism, Regio-, and Diastereoselectivity of Rh(III)-Catalyzed Cyclization Reactions of N‑Arylnitrones with Alkynes: A Density Functional Theory Study” Li, Y.; Shan, C.; Yang, Y.-F.; Shi, F.; Qi, X.; Houk, K. N.*; Lan, Y.* J. Phys. Chem. A 2017, 121, 4496-4504. ( DOI: 10.1021/acs.jpca.7b01020)
(61) “Bioinspired Asymmetric Synthesis of Hispidanin A” Li, F.; Tu, Q.; Chen, S.; Zhu, L.; Lan, Y.*; Gong, J.*; Yang, Z.* Angew. Chem. Int. Ed. 2017, 56, 5844-5848. (DOI: 0.1002/anie.201700838)
(60) “C−O Functionalization of α‑Oxyboronates: A Deoxygenative gemDiborylation and gem-Silylborylation of Aldehydes and Ketones” Wang, L.; Zhang, T.; Sun, W.; He, Z.; Xia, C.; Lan, Y.*; Liu, C.* J. Am. Chem. Soc. 2017, 139, 5257-5264. (DOI: 10.1021/jacs.7b02518)
(59) “Mononuclear or Dinuclear? Mechanistic Study of the ZincCatalyzed Oxidative Coupling of Aldehydes and Acetylenes” Yue, X.; Qi, X.; Bai, R.; Lei, A.*; Lan, Y.* Chem. Eur. J. 2017, 23, 6419-6425. (DOI: 10.1002/chem.201700733)
(58) “Mechanism of Alkaline Earth Metal Catalyzed Hydroboration of Carbodiimides: A Theoretical Study” Xu, D.; Shan, C.; Bai, R.*; Lan, Y.* Chin. J. Org. Chem. 2017, 37, 1231-1236. (DOI: 10.6023/cjoc201701033)
(57) “Regioselective a-Addition of Deconjugated Butenolides: Enantioselective Synthesis of Dihydrocoumarins” Wu, B.; Yu, Z.; Gao, X.; Lan, Y.*; Zhou, Y.* Angew. Chem. Int. Ed. 2017, 56, 4006-4010. (DOI:10.1002/anie.201700437)
(56) “Stabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical–Radical Cross-Coupling” Qi, X.; Zhu, L.; Bai, R.*; Lan, Y.* Sci. Rep. 2017, 7, 43579. (DOI: 10.1038/srep43579)
(55) “Thiolate–palladium(IV) or sulfonium–palladate(0)? A theoretical study on the mechanism of palladium-catalyzed C–S bond formation reactions” Xu, D.; Qi, X.; Duan, M.; Yu, Z.; Zhu, L.; Shan, C.; Yue, X.; Bai, R.*; Lan, Y.* Org. Chem. Front. 2017, 4, 943-950. (DOI: 10.1039/c6qo00841k)
(54) “Room-Temperature Coupling/Decarboxylation Reaction of α‑Oxocarboxylates with α‑Bromoketones: Solvent-Controlled Regioselectivity for 1,2- and 1,3-Diketones” He, Z.; Qi, X.; She, Z.; Zhao, Y.; Li, S.; Tang, J.; Gao, G.*; Lan, Y.*; You, J.* J. Org. Chem. 2017, 82, 1403-1411. (DOI: 10.1021/acs.joc.6b02575)
(53) “Application of Gausian Software in Organic Chemistry Teaching in Senior High School” Li, Y.;* Qi, X.; Lan, Y.* Chin. J. Chem. Edu. 2017, 38(13), 43. (DOI: 10.13884/J.1003-3807hxjy.2016120022)
(52) “Biomimetically inspired asymmetric total synthesis of (+)-19-dehydroxyl arisandilactone A” Han, Y.; Jiang, Y.; Li, Y.; Yu, H.; Tong, B.; Niu, Z.; Zhou, S.; Liu, S.; Lan, Y.;* Chen, J.;* Yang, Z.;* Nat. Commun. 2017, 8, 14233. (DOI: 10.1038/ncomms14233)
(51) “Ligand effect on nickle-catalyzed reductive alkyne-aldehyde coupling reactions: a computational study. ” Luo, X.; Li, Y.; Qi, X.; Zhu, L.; Chen, C.;* Lan, Y.* Sci. Sin. Chem. 2017, 47, 341-349. (DOI:10.1360/N032016-00129)
(50) “Computational Investigation of the Role Played by Rhodium(V) in the Rhodium(III)-Catalyzed ortho-Bromination of Arenes” Zhang, T.; Qi, X.; Liu, S.; Bai, R.; * Liu, C.; * Lan, Y.* Chem.-Eur. J. 2017, 23, 2690-2699. (DOI: 10.1002/chem.201605188)
(49) “Readily Accessible and Highly Efficient Ferrocene-Based AminoPhosphine-Alcohol (f-Amphol) Ligands for Iridium-Catalyzed Asymmetric Hydrogenation of Simple Ketones” Yu, J.; Duan, M.; Wu, W.;Qi, X. ; Xue, P.; Lan, Y.;* Dong, X-Q.;* Zhang, X.;* Chem.-Eur. J. 2017, 23, 970-975. (DOI: 10.1002/chem.201604855)
(48) “C8–H bond activation vs. C2–H bond activation: from naphthyl amines to lactams” Shi, R.; Lu, L.; Xie, H.; Yan, J.; Xu, T.; Zhang, H.; Qi, X.; Lan, Y.*; Lei, A.* Chem. Commun. 2016, 52, 13307. (DOI: 10.1039/c6cc06358f)
(47) “Mild Acylation of C(sp3)−H and C(sp2)−H Bonds under Redox-Neutral Rh(III) Catalysis” Yu, S.; Li, Y.; Kong, L.; Zhou, X.; Tang, G.; Lan, Y.;* Li, X.* ACS Catal. 2016, 6, 7744-7748. (DOI: 10.1021/acscatal.6b02668)
(46) “Effective Chirality Transfer in [3+2] Reaction between AllenylRhodium and Enal: Mechanistic Study Based on DFT Calculations” Qi, X.; Liu, S.; Zhang, T.; Long, R.; Huang, J.; Gong, J.; Yang, Z.;* Lan, Y.* J. Org. Chem. 2016, 81, 8306-8311. (DOI: 10.1021/acs.joc.6b01429)
(45) “Asymmetric Transfer Hydrogenation of Imines using Alcohol: Efficiency and Selectivity are Influenced by the Hydrogen Donor” Pan, H. J.; Zhang, Y.; Shan, C.; Yu, Z.; Lan, Y.;* Zhao, Y.* Angew. Chem. Int. Ed. 2016, 55, 9615-9619. (DOI:10.1002/anie.201604025)
(44) “Reactivity of Single-Walled Carbon Nanotubes in the Diels–Alder Cycloaddition Reaction: Distortion–Interaction Analysis along the Reaction Pathway” Li, Y.; Osuna, S.; Garcia-Borràs, M.; Qi, X.; Liu, S.; Houk, K. N.;* Lan, Y.* Chem.-Eur. J. 2016, 22, 12819-12824. (DOI: 10.1002/chem.201601799)
(43) “Iridium Catalysts with f‑Amphox Ligands: Asymmetric Hydrogenation of Simple Ketones” Wu, W.; Liu, S.; Duan, M.; Tan, X.; Chen, C.; Xie, Y.; Lan, Y.;* Dong, X.-Q.; Zhang, X.* Org. Lett. 2016, 18, 2938-2941. (DOI: 10.1021/acs.orglett.6b01290)
(42) “Computational Studies on an Aminomethylation Precursor: (Xantphos)Pd(CH2NBn2)+” Qi, X.; Liu, S.; Lan, Y.* Organometallics 2016, 35, 1582-1585. (DOI: 10.1021/acs.organomet.6b00234)
(41) “Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp3)-H and C(sp2)-H under Rhodium(III) Catalysis” Yu, S.; Tang, G.; Li, Y.; Zhou, X.; Lan, Y.;* Li, X.* Angew. Chem. Int. Ed. 2016, 55, 8696-8700. (DOI: 10.1002/anie.201602224)
(40) “Efficient Synthesis of Dimeric Oxazoles, Piperidines and Tetrahydroisoquinolines from N-Substituted 2-Oxazolones” He, Y.;* Agarwal, P. K.; Kiran, I. N.; Yu, R.; Cao, B.; Zou, C.; Zhou, X.; Xu, H.; Xu, B.; Zhu, L.; Lan, Y.;* Nicolaou, K. C.* Chem.-Eur. J. 2016, 22, 7696-7701. (DOI: 10.1002/chem.201601471)
(39) “Regio- and Stereoselective Syntheses of 7-Oxabicyclo[2.2.1]heptanes via a Gold(I)-Catalyzed Cycloisomerization of Alkynediols: Asymmetric Total Synthesis of Farnesiferol C” Gu, Y.-Q.; Zhang, P.-P.; Fu, J.-K.; Liu, S.; Lan, Y.*; Gong, J.-X.*; Yang, Z.* Adv. Synth. Catal. 2016, 358, 1392-1397. (DOI: 10.1002/adsc.201600218)
(38) “Mechanism of Ruthenium-Catalyzed Direct Arylation of C−H Bonds in Aromatic Amides: A Computational Study” Shan, C.; Luo, X.; Qi, X.; Liu, S.; Li, Y.; Lan, Y.* Organometallics 2016, 35, 1440-1445. (DOI: 10.1021/acs.organomet.6b00064)
(37) “Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C−H Bond Activation” Gao, B.; Liu, S.; Lan, Y.*; Huang, H.* Organometallics 2016, 35, 1480-1487. (DOI: 10.1021/acs.organomet.6b00072)
(36) “Mechanism of Rhodium-Catalyzed Formyl Activation: A Computational Study” Luo, X.; Bai, R.; Liu, S.; Shan, C.; Chen, C.; Lan, Y.* J. Org. Chem. 2016, 81, 2320-2326. (DOI: 10.1021/acs.joc.5b02828)
(35) “Mechanism and electronic effect for the synthesis of 6-aroylated phenanthridines: a theoretical study” Xu, T.; Qi, X.; Lan, Y.* Sci. Sin. Chem. 2016, 46, 616-622. (DOI: 10.1360/N032015-00217)
(34) “Rhodium-Catalyzed Hetero-(5+2) Cycloaddition of Vinylaziridines and Alkynes: A Theoretical View of the Mechanism and Chirality Transfer” Zhu, L.; Qi, X.; Lan, Y.* Organometallics 2016, 35, 771-777. (DOI: 10.1021/acs.organomet.6b00007)
(33) “Rhodium(III)-Catalyzed Annulation between N‑Sulfinyl Ketoimines and Activated Olefins: C−H Activation Assisted by an Oxidizing N−S Bond” Wang, Q.; Li, Y.; Qi, Z.; Xie, F.; Lan, Y.*; Li, X.* ACS Catal. 2016, 6, 1971-1980. (DOI: 10.1021/acscatal.5b02297)
(32) “Gold(I)-Catalyzed Angle Strain Controlled Strategy to Furopyran Derivatives from Propargyl Vinyl Ethers: Insight into the Regioselectivity of Cycloisomerization” Jin, S.; Jiang, C.; Peng, X.; Shan, C.; Cui, S.; Niu, Y.; Liu, Y.; Lan, Y.*; Liu, Y.*; Cheng, M.* Org. Lett. 2016, 18, 680-683. (DOI: 10.1021/acs.orglett.5b03641)
(31) “Mechanism of Synergistic Cu(II)/Cu(I)-Mediated Alkyne Coupling: Dinuclear 1,2-Reductive Elimination after Minimum Energy Crossing Point” Qi, X.; Bai, R.; Zhu, L.; Jin, R.; Lei, A.; Lan, Y.* J. Org. Chem. 2016, 81, 1654-1660. (DOI: 10.1021/acs.joc.5b02797)
(30) “Iron-Catalyzed Decarboxylative (4+1) Cycloadditions: Exploiting the Reactivity of Ambident Iron-Stabilized Intermediates” Wang, Q.; Qi, X.; Lu, L. Q.*; Li, T. R.; Yuan, Z. G.; Zhang, K.; Li, B. J.; Lan, Y.*; Xiao, W. J.* Angew. Chem. Int. Ed. 2016, 55, 2840-2844. (DOI: 10.1002/anie.201510413)
(29) “Regiodivergent Enantioselective γ‑Additions of Oxazolones to 2,3-Butadienoates Catalyzed by Phosphines: Synthesis of α,α-Disubstituted α‑Amino Acids and N,O‑Acetal Derivatives” Wang, T.; Yu, Z.; Hoon, D. L.; Phee, C. Y.; Lan, Y.*; Lu, Y.* J. Am. Chem. Soc. 2016, 138, 265-271. (DOI: 10.1021/jacs.5b10524)
(28) “Mechanism, chemoselectivity and enantioselectivity for the rhodium-catalyzed desymmetric synthesis of hydrobenzofurans: a theoretical study” Yu, Z.; Qi, X.; Li, Y.; Liu, S.; Lan, Y.* Org. Chem. Front. 2016, 3, 209-216. (DOI: 10.1039/c5qo00334b)
(27) “Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine” Wu, K.; Huang, Z.; Qi, X.; Li, Y.; Zhang, G.; Liu, C.; Yi, H.; Meng, L.; Bunel, E. E.; Miller, J. T.; Pao, C. W.; Lee, J. F.; Lan, Y.*; Lei, A.* Sci. Adv. 2015, 1, e1500656. (DOI: 10.1126/sciadv.1500656)
(26) “Silver Migration Facilitates Isocyanide-Alkyne [3+2] Cycloaddition Reactions: Combined Experimental and Theoretical Study” Qi, X.; Zhang, H.; Shao, A.; Zhu, L.; Xu, T.; Gao, M.*; Liu, C.*; Lan, Y.* ACS Catal. 2015, 5, 6640-6647. ( DOI: 10.1021/acscatal.5b02009)
(25) “Towards a general diastereoselective route to oxabicyclo[3.2.1]octanes via a gold-catalysed cascade reaction” Fu, J.; Gu, Y.; Yuan, H.; Luo, T.; Liu, S.; Lan, Y.*; Gong, J.*; Yang, Z.* Nat. Commun. 2015, 6, 8617. (DOI: 10.1038/ncomms9617)
(24) “Development of a Rhodium(II)-Catalyzed Chemoselective C(sp3)-H Oxygenation” Lin, Y.; Zhu, L.; Lan, Y.*; Rao, Y.* Chem.-Eur. J. 2015, 21, 14937-14942. (DOI: 10.1002/chem.201502140.)
(23) “Diastereoselective Synthesis of Cyclopentanoids: Applications to the Construction of the ABCD Tetracyclic Core of Retigeranic Acid” A Zhang, J.; Wang, X.; Li, S.; Li, D.; Liu, S.; Lan, Y.*; Gong, J.*; Yang, Z.* Chem.-Eur. J. 2015, 21, 12596-12600. (DOI: 10.1002/chem.201502423)
(22) “Distortion–interaction analysis along the reaction pathway to reveal the reactivity of the Alder-ene reaction of enes” Jin, R.; Liu, S.; Lan, Y.* RSC Adv. 2015, 5, 61426-61435. (DOI: 10.1039/c5ra10345b)
(21) “Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings” Wang, T.; Yu, Z.; Hoon, D. L.; Huang, K.-W.; Lan, Y.*; Lu, Y.* Chem. Sci. 2015, 6, 4912-4922. (DOI: 10.1039/c5sc01614b)
(20) “Mechanism and selectivity for zinc-mediated cycloaddition of azides with alkynes: a computational study” Li, Y.; Qi, X.; Lei, Y.; Lan, Y.* RSC Adv. 2015, 5, 49802-49808. (DOI: 10.1039/c5ra02703a)
(19) “The Mechanism of N-O Bond Cleavage in Rhodium-Catalyzed C-H Bond Functionalization of Quinoline N-oxides with Alkynes:A Computational Study” Li, Y.; Liu, S.; Qi, Z.; Qi, X.; Li, X.*; Lan, Y.* Chem.-Eur. J. 2015, 21, 10131-10137. (DOI: 10.1002/chem.201500290)
(18) “Dinuclear versus mononuclear pathways in zinc mediated nucleophilic addition: a combined experimental and DFT study” Qi, X.; Li, Y.; Zhang, G.; Li, Y.; Lei, A.*; Liu, C.*; Lan, Y.* Dalton Trans. 2015, 44, 11165-11171. (DOI: 10.1039/c5dt01366f)
(17) “Tuning radical reactivity using iodine in oxidative C(sp3)–H/C(sp)–H cross-coupling: an easy way toward the synthesis of furans and indolizines” Tang, S.; Liu, K.; Long, Y.; Qi, X.; Lan, Y.*; Lei, A.* Chem. Commun. 2015, 51, 8769-8772. (DOI: 10.1039/c5cc01825k)
(16) “Nickel-Catalyzed Selective Oxidative Radical Cross-Coupling: An Effective Strategy for Inert Csp3−H Functionalization” Liu, D.; Li, Y.; Qi, X.; Liu, C.; Lan, Y.*; Lei, A.* Org. Lett. 2015, 17, 998-1001. (DOI: 10.1021/acs.orglett.5b00104)
(15) “Bimetallic zinc complex–active species in coupling of terminal alkynes with aldehydes via nucleophilic addition/Oppenauer oxidation” Yuan, J.; Wang, J.; Zhang, G.; Liu, C.; Qi, X.; Lan, Y.*; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lei, A.* Chem. Commun. 2015, 51, 576-579. (DOI: 10.1039/c4cc08152h)
(14) “Revealing the halide effect on the kinetics of the aerobic oxidation of Cu(I) to Cu(II)” Deng, Y.; Zhang, G.; Qi, X.; Liu, C.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lan, Y.*; Lei, A.* Chem. Commun. 2015, 51, 318-321. (DOI: 10.1039/c4cc05720a)
(13) “Transition-Metal-Free Formal Decarboxylative Coupling of a-Oxocarboxylates with a-Bromoketones under Neutral Conditions: A Simple Access to 1,3-Diketones” He, Z.; Qi, X.; Li, S.; Zhao, Y.; Gao, G.*; Lan, Y.*; Wu, Y.; Lan, J.; You, J.* Angew. Chem. Int. Ed. 2015, 54, 855-859. (DOI: 10.1002/anie.201409361)
(12) “Rhodium-Catalyzed C−H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C−N Bond: A Combination of Experimental and Theoretical Studies” Yu, S.; Liu, S.; Lan, Y.*; Wan, B.*; Li, X.* J. Am. Chem. Soc. 2015, 137, 1623-1631. (DOI: 10.1021/ja511796h)
(11) “Transition-Metal-Assisted Radical/Radical Cross-Coupling: A New Strategy to the Oxidative C(sp3)−H/N−H Cross-Coupling” Zhou, L.; Tang, S.; Qi, X.; Lin, C.; Liu, K.; Liu, C.; Lan, Y.*; Lei, A.* Org. Lett. 2014, 16, 3404-3407. (DOI: 10.1021/ol501485f)
(10) “Carbon-Centered Radical Addition to O=C of Amides or Esters as a Route to CO Bond Formations” Liu, D.; Tang, S.; Yi, H.; Liu, C.; Qi, X.; Lan, Y.*; Lei, A.* Chem.-Eur. J. 2014, 20, 15605-15610. (DOI: 10.1002/chem.201404607)
(9) “Chemoselective Carbophilic Addition of a-Diazoesters through Ligand-Controlled Gold Catalysis” Xi, Y.; Su, Y.; Yu, Z.; Dong, B.; McClain, E. J.; Lan, Y.*; Shi, X.* Angew. Chem. Int. Ed. 2014, 53, 9817-9821. (DOI: 10.1002/anie.201404946)
(8) “Visible-Light-Mediated Decarboxylation/Oxidative Amidation of α-Keto Acids with Amines under Mild Reaction Conditions Using O2” Liu, J.; Liu, Q.; Yi, H.; Qin, C.; Bai, R.; Qi, X.; Lan, Y.*; Lei, A.* Angew. Chem. Int. Ed. 2014, 53, 502-506. (DOI: 10.1002/anie.201308614)
(7) “Cu(II)−Cu(I) Synergistic Cooperation to Lead the Alkyne C−H Activation” Bai, R.; Zhang, G.; Yi, H.; Huang, Z.; Qi, X.; Liu, C.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lan, Y.*; Lei, A.* J. Am. Chem. Soc. 2014, 136, 16760-16763. (DOI: 10.1021/ja5097489)
(6) “Asymmetric total synthesis of (-)-lingzhiol via a Rh-catalysed [3+2] cycloaddition” Long, R.; Huang, J.; Shao, W.; Liu, S.; Lan, Y.*; Gong, J.*; Yang, Z.* Nat. Commun. 2014, 5, 5707. (DOI: 10.1038/ncomms6707)
(5) “Theoretical study of the electron-donating effects of thiourea ligands in catalysis” Liu, S.; Lei, Y.; Yang, Z.*; Lan, Y.* J. Mol. Struct. 2014, 1074, 527-533. (DOI:10.1016/j.molstruc.2014.06.034)
(4) “Hexahapto-chromium complexes of graphene: a theoretical study” Liu, S.; Lei, Y.; Li, Y.; Zhang, T.; Wang, H.; Lan, Y.* RSC Adv. 2014, 4, 28640. (DOI: 10.1039/c4ra03702b)
(3) “What Controls Stereoselectivity and Reactivity in the Synthesis of a trans-Decalin with a Quaternary Chiral Center via the Intramolecular Pauson−Khand Reaction: A Theoretical Study” Liu, S.; Shen, H.; Yu, Z.; Shi, L.; Yang, Z.*; Lan, Y.* Organometallics 2014, 33, 6282-6285. (DOI: 10.1021/om500840q )
(2) “Reactivity for the Diels−Alder Reaction of Cumulenes: A Distortion-Interaction Analysis along the Reaction Pathway” Liu, S.; Lei, Y.; Qi, X.; Lan, Y.* J. Phys. Chem. A 2014, 118, 2638-2645. (DOI: 10.1021/jp411914u)
(1) “Mechanism of Rhodium-Catalyzed Carbon−Silicon Bond Cleavage for the Synthesis of Benzosilole Derivatives: A Computational Study” Yu, Z.; Lan, Y.* J. Org. Chem. 2013, 78, 11501-11507. (DOI: 10.1021/jo402070f)
（二）第一作者论文
(8) “Why Nature Eschews the Concerted [2+2+2] Cycloaddition of a Nonconjugated Cyanodiyne. Computational Study of a Pyridine Synthesis Involving an Ene−Diels−Alder−Bimolecular Hydrogen- Transfer Mechanism” Lan, Y.; Danheiser, R. L.*; Houk, K. N.* J. Org. Chem. 2012, 77, 1533-1538. (DOI: 10.1021/jo202424n)
(7) “Theoretical study of Pd(0)-catalyzed carbohalogenation of alkenes: mechanism and origins of reactivities and selectivities in alkyl halide reductive elimination from Pd(II) species” Lan, Y.; Liu, P.; Newman, S. G.; Lautens, M.*; Houk, K. N.* Chem. Sci. 2012, 3, 1987-1995. (DOI: 10.1039/c2sc20103h)
(6) “Computational Methods To Calculate Accurate Activation and Reaction Energies of 1,3-Dipolar Cycloadditions of 24 1,3-Dipoles” Lan, Y.; Zou, L.; Cao, Y.; Houk, K. N.* J. Phys. Chem. A 2011, 115, 13906-13920. (DOI: 10.1021/jp207563h)
(5) “Mechanism of the Palladium-Catalyzed Addition of Arylboronic Acids to Enones: A Computational Study” Lan, Y.; Houk, K. N.* J. Org. Chem. 2011, 76, 4905-4909. (DOI: 10.1021/jo2002903)
(4) “Extraordinary Difference in Reactivity of Ozone (OOO) and Sulfur Dioxide (OSO): A Theoretical Study” Lan, Y.; Wheeler, S. E.; Houk, K. N.* J. Chem. Theory Comput. 2011, 7, 2104-2111. (DOI: 10.1021/jo902163v)
(3) “A Theoretical Investigation on the Mechanism of a Palladium-Mediated Formal 6π Electrocyclic Synthesis of 9,10-Dihydrophenanthrenes” Lan, Y.; Wang, C.; Sowa, J. R., Jr.; Wu, Y. D.* J. Org. Chem. 2010, 75, 951-954. (DOI: 10.1021/jo902163v)
(2) “Mechanism and Stereoselectivity of the Stepwise 1,3-Dipolar Cycloadditions between a Thiocarbonyl Ylide and Electron-Deficient Dipolarophiles: A Computational Investigation” Lan, Y.; Houk, K. N.* J. Am. Chem. Soc. 2010, 132, 17921-17927. (DOI: 10.1021/ja108432b)
(1) “On the Mechanism of the Palladium Catalyzed Intramolecular Pauson-Khand-Type Reaction” Lan, Y.; Deng, L.; Liu, J.; Wang, C.; Wiest, O.; Yang, Z.*; Wu, Y. D.* J. Org. Chem. 2009, 74, 5049-5058. (DOI: 10.1021/jo900919v)
（三）共同作者论文
(25) “Enantioselective Trapping of Pd-Containing 1,5-Dipoles by Photogenerated Ketenes: Access to 7‑Membered Lactones Bearing Chiral Quaternary Stereocenters” Wei, Y.; Liu, S.; Li, M.-M.; Li, Y.; Lan, Y.; Lu, L. Q.*; Xiao, W.-J.* J. Am. Chem. Soc. 2019, 141, 133-137.
(24) “Diversity-oriented synthesis of imidazo[2,1-a]isoquinolines” Mai, S.; Luo, Y.; Huang, X.; Shu, Z.; Li, B.; Lan, Y.; Song, Q.* Chem. Commun. 2018, 54, 10240-10243.
(23) “Annulation cascade of arylnitriles with alkynes to stable delocalized PAH carbocations via intramolecular rhodium migration” Yin, J.; Zhou, F.; Zhu, L.; Yang, M.; Lan, Y.; You, J.* Chem. Sci. 2018, 9, 5488-5493. (DOI: 10.1039/c8sc01963k)
(22) “Oxidation-induced C–H amination leads to a new avenue to build C–N bonds” Yi, H.; Tang, Z.; Bian, C.; Chen, H.; Qi, X.; Yue, X.; Lan, Y.; Lee, J.-F.; Lei, A.* Chem. Commun. 2017, 53, 8984-8987. (DOI: 10.1039/c7cc04955b)
(21) “Coordination strategy-induced selective C–H amination of 8-aminoquinolines” Yi, H.; Chen, H.; Bian, C.; Tang, Z.; Singh, A. K.; Qi, X.; Yue, X.; Lan, Y.; Lee, J.-F.; Lei, A.* Chem. Commun. 2017, 53, 6736-6739. (DOI: 10.1039/c7cc02601c)
(20) “Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates” Yi, H.; Yang, D.; Xin, J.; Qi, X.; Lan, Y.; Deng, Y.*; Pao, C.-W.; Lee, J.-F.; Lei, A.* Nat. Commun. 2017, 8, 14794. (DOI: 10.1038/ncomms14794)
(19) “Highly enantioselective nitro-Mannich reaction of ketimines under phase-transfer catalysis” Wang, B.; Xu, T.; Zhu, L.; Lan, Y.; Wang, J.; Lu, N.; Wei, Z.; Lin, Y.*; Duan, H. Org. Chem. Front. 2017, 4, 1266-1271. (DOI: 10.1039/C7QO00124J)
(18) “Aromatic C–H bond cleavage by using a Cu(I) ate-complex” Zhang, G.; Yi, H.; Xin, J.; Deng, Y.; Bai, R.; Huang, Z.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Qi, X.; Lan, Y.; Lei, A.* Org. Chem. Front. 2016, 3, 975-978. (DOI: 10.1039/c6qo00201c)
(17) “Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation” Hu, X.-Q.; Qi, X.; Chen, J.-R.*; Zhao, Q.-Q.; Wei, Q.; Lan, Y.; Xiao, W.-J. Nat. Commun. 2016, 7, 11188. (DOI: 10.1038/ncomms11188)
(16) “Homolytic cleavage of the O–Cu(II) bond: XAFS and EPR spectroscopy evidence for one electron reduction of Cu(II) to Cu(I)” Yi, H.; Zhang, G.; Xin, J.; Deng, Y.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Qi, X.; Lan, Y.; Lee, J.-F.; Lei, A.* Chem. Commun. 2016, 52, 6914-6917. (DOI: 10.1039/c6cc01413e)
(15) “Tuning the Reactivity of Radical through a Triplet Diradical Cu(II) Intermediate in Radical Oxidative Cross-Coupling” Zhou, L.; Yi, H.; Zhu, L.; Qi, X.; Jiang, H.; Liu, C.; Feng, Y.; Lan, Y.; Lei, A.* Sci. Rep. 2015, 5, 15934. (DOI: 10.1038/srep15934)
(14) “Carboxylate-Assisted C(sp3)−H Activation in Olefin Metathesis-Relevant Ruthenium Complexes” Cannon, J. S.; Zou, L.; Liu, P.; Lan, Y.; O'Leary, D. J.; Houk, K. N.*; Grubbs, R. H.* J. Am. Chem. Soc. 2014, 136, 6733-6743. (DOI: 10.1021/ja5021958)
(13) “Mechanism and Enantioselectivity in Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β‑Substituted Cyclic Enones: Insights from Computation and Experiment” Holder, J. C.; Zou, L.; Marziale, A. N.; Liu, P.; Lan, Y.; Gatti, M.; Kikushima, K.; Houk, K. N.*; Stoltz, B. M.* J. Am. Chem. Soc. 2013, 135, 14996-15007. (DOI: 10.1021/ja401713g)
(12) “Understanding Reactivity and Stereoselectivity in Palladium-Catalyzed Diastereoselective sp3 C−H Bond Activation: Intermediate Characterization and Computational Studies” Giri, R.; Lan, Y.; Liu, P.; Houk, K. N.*; Yu, J. Q.* J. Am. Chem. Soc. 2012, 134, 14118-14126. (DOI: 10.1021/ja304643e)
(11) “Decomposition Pathways of Z-Selective Ruthenium Metathesis Catalysts” Herbert, M. B.; Lan, Y.; Keitz, B. K.; Liu, P.; Endo, K.; Day, M. W.; Houk, K. N.*; Grubbs, R. H.* J. Am. Chem. Soc. 2012, 134, 7861-7866. (DOI: 10.1021/ja301108m)
(10) “A novel self-promoted Morita-Baylis-Hillman-like dimerization” Li, Q.; Wongkhan, K.; Luo, X.; Batsanov, A. S.; Howard, J. A. K.; Lan, Y.; Wu, Y.*; Marder, T. B.*; Lei, A.* Chin. Sci. Bull. 2010, 55, 2794-2798. (DOI: 10.1007/s11434-010-3270-9)
(9) “Base-Induced Mechanistic Variation in Palladium-Catalyzed Carbonylation of Aryl Iodides” Hu, Y.; Liu, J.; Lu, Z.; Luo, X.; Zhang, H.; Lan, Y.; Lei, A.* J. Am. Chem. Soc. 2010, 132, 3153-3158. (DOI: 10.1021/ja909962f)
(8) “Revealing a Second Transmetalation Step in the Negishi Coupling and Its Competition with Reductive Elimination: Improvement in the Interpretation of the Mechanism of Biaryl Syntheses” Liu, Q.; Lan, Y.; Liu, J.; Li, G.; Wu, Y. D.*; Lei, A.* J. Am. Chem. Soc. 2009, 131, 10201-10210. (DOI: 10.1021/ja903277d)
(7) “Revelation of the Difference between Arylzinc Reagents Prepared from Aryl Grignard and Aryllithium Reagents Respectively: Kinetic and Structural Features” Jin, L.; Liu, C.; Liu, J.; Hu, F.; Lan, Y.; Batsanov, A. S.; Howard, J. A.; Marder, T. B.*; Lei, A.* J. Am. Chem. Soc. 2009, 131, 16656-16657. (DOI: 10.1021/ja908198d)
(6) “Stereoselective Construction of an Unprecedented 7-8 Fused Ring System in Micrandilactone A by [3,3]-Sigmatropic Rearrangement” Zhang, Y.-D.; Ren, W.-W.; Lan, Y.; Xiao, Q.; Wang, K.; Xu, J.; Chen, J.-H.*; Yang, Z.* Org. Lett. 2008, 10, 665-668. (DOI: 10.1021/ol703126q)
(5) “Effect of Lithium Chloride on Tuning the Reactivity of Pauson–Khand Reactions Catalyzed by Palladium–Tetramethylthiourea” Yang, Z.*; Lei, A.*; Chen, J.-H.*; Deng, L.-J.; Liu, J.; Huang, J.-Q.; Hu, Y.; Chen, M.; Lan, Y. Synthesis 2007, 2007, 2565-2570. (DOI: 10.1055/s-2007-983796)
(4) “Synthesis of Thiourea-Oxazolines, a New Class of Chiral S,N-Heterobidentate Ligands: Application in Pd-Catalyzed Asymmetric Bis(methoxycarbonylation) of Terminal Olefins” Liang, B.; Liu, J.; Gao, Y.-X.; Wongkhan, K.; Shu, D.-X.; Lan, Y.; Li, A.; Batsanov, A. S.; Howard, J. A. H.; Marder, T. B.*; Chen, J.-H.*; Yang, Z.* Organometallics 2007, 26, 4756-4762. (DOI: 10.1021/om700311x)
(3) “Convenient and Efficient Synthesis of 1,1-Bis-(4-alkylthiophenyl)-1-alkenes via Tandem Friedel–Crafts Acylation and Alkylation of Sulfides and Acyl Chlorides” Xu, J.*; Xia, J.; Lan, Y. Synth. Commun. 2005, 35, 2347-2353. (DOI: 10.1080/00397910500187373)
(2) “Mildly and Highly Selective Reductive Deoxygenation of para-Di- and Monoalkylaminophenyl Ketones by Borane” Wei, T.; Lan, Y.; Xu, J.* Heteroat. Chem. 2005, 16, 2-5. (DOI: 10.1002/hc.20062)
(1) “Chiral Oxazaborolidine-catalyzed Asymmetric Borane Reduction of Alkyl 4-Dialkylaminophenyl Ketones” Xu, J.-X.*; Lan, Y.; Wei, T.-Z.; Zhang, Q.-H. Chin. J. Chem. 2005, 23, 1457-1461. (DOI: 10.1002/cjoc.200591457)
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