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        白若鹏

讲师

 

Bai Ruopeng

Ph. D.

Assistant Professor

 

Office:

LC220, College of Chemistry and Chemical Engineering, Huxi Campus, Chongqing University, 401331

 

Work Experience:

2016.09-, Assistant Professor, College of Chemistry and Chemical Engineering, Chongqing University

 

Education:

2011.09-2016.06, Ph. D., College of Chemistry and Molecular Science, Wuhan University, Supervisor: Prof. Aiwen Lei

2007.09-2011.06, B.Sc., Department of Chemistry, University of Science and Technology of China

 

Research Interest:

 

Theory directed mechanism investigation of transition metal catalyzed coupling reactions

Transition metal catalyzed hydrotransition reactions

Bulky ligand design and application

 

Publications:

 

“Ni(I)–Ni(III) vs Ni(II)–Ni(IV): Mechanistic Study of Ni-catalyzed Alkylation of Benzamides with Alkyl Halides.” Li, Yingzi; Yu, Da-Gang*; Bai, Ruopeng*; Lan, Yu*, Organic Chemistry Frontiers 2018, 5, 615-622.

 

“On the Mechanism of Copper-Catalyzed Oxytrifluoromethylation of Allylamines with CO2: A Computational Study.” Zhu, Lei; Ye, Jian-Heng; Duan, Meng; Qi, Xiaotian; Zou, Lufeng; Bai, Ruopeng*; Lan, Yu*, Organic Chemistry Frontiers 2018, 5, 633-639.

 

“Ni-Catalyzed C–F Bond Functionalization of Unactivated Aryl Fluorides and Corresponding Coupling with Oxazoles.” Yin, Youzhi; Yue, Xiaoyu; Zhong, Qi; Jiang, Hanmin; Bai, Ruopeng*; Lan, Yu*; Zhang Hua*, Advanced Synthesis & Catalysis 2018, 5, DOI: 10.1002/adsc.201701506.

 

“C–H bond cleavage occurring on a Rh(V) intermediate: a theoretical study of Rh-catalyzed arene azidation.” Liu, Song; Qi, Xiaotian; Qu, Ling-Bo; Bai, Ruopeng*; Lan, Yu*, Catalysis Science & Technology 2018, 5, DOI: 10.1002/adsc.201701506.

 

“Insights into disilylation and distannation: sequence influence and ligand/steric effects on Pd-catalyzed difunctionalization of carbenes.” Yue, Xiaoyu; Shan, Chunhui; Qi, Xiaotian; Luo, Xiaoling; Zhu, Lei; Zhang, Tao; Li, Yuanyuan; Li, Yingzi; Bai, Ruopeng*; Lan, Yu*, Dalton Transactions 2018, 47, 1819-1826.

 

 “Mechanism of Rhodium-Catalyzed C–H Functionalization: Advances in Theoretical Investigation.” Qi, Xiaotian; Li, Yingzi; Bai, Ruopeng; Lan, Yu*, Accounts of Chemical Research 201750, 2799–2808.

 

“From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3+2] Cycloaddition.” Duan, Meng; Zhu, Lei; Qi, Xiaotian; Yu, Zhaoyuan; Li, Yingzi; Bai, Ruopeng*; Lan, Yu*, Scientific Reports 2017, 7, 7619.

 

“Stabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical-Radical Cross-Coupling.” Qi, Xiaotian; Zhu, Lei; Bai, Ruopeng*; Lan, Yu*, Scientific Reports 2017, 7, 43579.

 

“Computational Investigation of the Role Played by Rh(V) in the Rh(III)-Catalyzed Ortho Bromination of Arenes.” Zhang, Tao; Qi, Xiaotian; Liu, Song; Bai, Ruopeng*; Liu, Chao*; Lan, Yu*, Chem.-Eur. J.”, 2017, 11, 2690-2699.

 

“Mononuclear or Dinuclear? Mechanistic Study of the Zinc-Catalyzed Oxidative Coupling of Aldehydes and Acetylenes.” Yue, Xiaoyu, Qi, Xiaotian; Bai, Ruopeng*; Lei, Aiwen*; Lan, Yu*, Chem.-Eur. J.”, 2017, 11, 6419-6425.

 

“Ir(III)/Ir(V) or Ir(I)/Ir(III) Catalytic Cycle? Steric-Effect-Controlled Mechanism for the para-C–H Borylation of Arenes.” Zhu, Lei; Qi, Xiaotian; Li, Yingzi; Duan, Meng; Zou, Lufeng; Bai, Ruopeng*; Liu, Chao*; Lan, Yu*, Organometallics, 2017, 11, 2107-2115.

 

“Bond Dissociation Energy Controlled s-Bond Metathesis in Alkaline-Earth-Metal Hydride Catalyzed Dehydrocoupling of Amines and Boranes: A Theoretical Study.” Xu, Dongdong; Qi, Xiaotian; Duan, Meng; Yu, Zhaoyuan; Zhu, Lei; Shan, Chunhui; Yue, Xiaoyu; Bai, Ruopeng*; Lan, Yu*, Inorganic Chemistry Frontiers 2017, 4, 1813-1820.

 

“Thiolate-Palladium(IV) or Sulfonium-Palladate(0)? A Theoretical Study on the Mechanism of Palladium-Catalyzed C-S Bond Formation Reactions.” Xu, Dongdong; Qi, Xiaotian; Duan, Meng; Yu, Zhaoyuan; Zhu, Lei; Shan, Chunhui; Yue, Xiaoyu; Bai, Ruopeng*; Lan, Yu*, Organic Chemistry Frontiers 2017, 4, 943-950.

 

“The Mechanism of Alkaline Earth Metal Catalyzed Hydroboration of Carbodiimides: A Theoretical Study.” Xu, Dongdong; Shan, Chunhui; Bai, Ruopeng*; Lan, Yu*; Chinese Journal of Organic Chemistry 2017, 37, 1231-1236.

 

“Mechanistic Insights into Copper-Catalyzed Trifluoromethylation of Aryl Boronic Acids: A Theoretical Study.” He, Xiaoqian; Shan, Chunhui; Bai, Ruopeng*; Lan, Yu*; Scientia Sinica Chimica 2017, 47, 859-864.

 

“C(sp(2))-C(sp(2)) Reductive Elimination from Well-Defined Diarylgold(lll) Complexes.” Kang, Kai; Liu, Shuanshuan; Xu, Ting; Wang, Decai; Leng, Xuebing ; Bai, Ruopeng; Lan, Yu*; Shen, Qilong*; Organometallics 2017, 36, 4727-4740.

 

“Mechanism of Rhodium-Catalyzed Formyl Activation: A Computational Study”, Luo, Xiaoling#; Bai, Ruopeng#; Liu, Song; Shan, Chunhui; Chen, Changguo*; Lan, Yu*, J. Org. Chem. 2016, 81, 2320-2326.

 

“Mechanism of Synergistic Cu(II)/Cu(I)-Mediated Alkyne Coupling: Dinuclear 1,2-Reductive Elimination after Minimum Energy Crossing Point. ” Qi, Xiaotian#; Bai, Ruopeng#; Zhu, Lei; Jin, Rui; Lei, Aiwen*; Lan, Yu*, J. Org. Chem. 2016, 81, 1654-1560.

 

 “Cu(II)/Cu(I)-Synergistic Cooperation to Lead the Alkyne C-H Activation”, Bai, Ruopeng; Zhang, Guanghui; Yi, Hong; Huang, Zhiliang; Qi, Xiaotian; Liu, Chao; Miller, Jeffrey T. ; Kropf, A. Jeremy ; Bunel, Emilio E.; Lan, Yu*; Lei, Aiwen*, J. Am. Chem. Soc. 2014, 16760-16763.

 

“Revealing the Metal-like Behavior of Iodine: An Iodide-Catalysed Radical Oxidative Alkenylation”, Tang, Shan; Wu, Yong; Liao, Wenqing; Bai, Ruopeng; Liu, Chao; Lei, Aiwen*, Chem. Commun., 2014, 4496-4499.

 

“Direct Observation of Reduction of Cu(II) to Cu(I) by Terminal Alkynes” Zhang, Guanghui; Yi, Hong; Zhang, Guoting; Deng, Yi; Bai, Ruopeng; Zhang, Heng; Miller, Jeffrey T.; Kropf, Arthur J.; Bunel, Emilio E.; Lei, Aiwen*. J. Am. Chem. Soc.  2014, 924–926.

 

“Visible-Light-Mediated Decarboxylation/Oxidative Amidation of a-Keto Acids with Amines under Mild Reaction Conditions Using O2” Liu, Jie; Liu, Qiang; Yi, Hong; Qin, Chu; Bai, Ruopeng; Qi, Xiaotian; Lan, Yu*; Lei, Aiwen*. Angew. Chem. Int. Ed. 2014, 502–506.

 

“Synthesis of Pyrroles by Click Reaction: Silver-Catalyzed Cycloaddition of Terminal Alkynes with Isocyanides ” Gao, Meng; He, Chuan; Chen, Hongyi; Bai, Ruopeng; Cheng, Ben; Lei, Aiwen*. Angew. Chem. Int. Ed. 2013, 6958–6961.

 

“Easy Access to Enamides: A Mild Nickel-Catalysed Alkene Isomerization of Allylamides. ” Wang, Lu; Liu, Chao; Bai, Ruopeng; Pan, Yani; Lei, Aiwen*. Chem. Commun. 2013, 7923-7925.

 

 “Influence of 12-crown-4 on the Oxygen Electrode of Aprotic Li-O2 Battery.” Wang Xiao-Chen, Wang Ying-Ming, Liu Wei, Bai Ruopeng, Liu Yan-Fang, Xiao Li*, Lu Jun-Tao, Zhuang Lin, Acta Phys. -Chim. Sin., 2016, 32, 343-348.