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高文亮 副教授,1996年毕业于桂林工学院应用化学系;2000年于河南师范大学获得理学硕士学位,研究方向为溶液热力学;2003年于南开大学获物理化学博士学位,研究方向为多相催化与环境催化;2004-2006在北京大学化学与分子工程学院进行博士后研究,主要从事微孔硼铝酸盐的合成及催化性能。2006年进入重庆大学化学化工学院进行科研教学工作,已发表SCI论文70余篇。

 

 

一、主讲课程:

① 本科课程:物理化学、晶体化学基础;

② 研究生课程:结晶化学导论。

二、研究兴趣:

1. 微孔催化材料的合成与改性

①八面体骨架分子筛:微孔硼铝酸盐的合成、酸碱性能调节及形貌控制合成;②氧化还原分子筛:过渡金属对八面体分子筛的同晶置换。③固体酸和固体碱:固体材料中酸性和碱性位点的构筑和修饰。

2. 催化剂表面结构、构效关系及其催化反应机理

①氧化还原反应:氧化还原分子筛在精细有机合成中的绿色催化;②酸碱催化:固体酸碱中心催化的相关反应;③催化机理:利用原位手段探索催化反应中固体结构、活性中间体、催化活性之间的构效关系。

三、联系方式:

电子邮箱:gaowl@cqu.edu.cn  联系电话:13452079116

四、科技论文:

1)通讯作者或第一作者

1.    Weilu Wang, Shixiang Hu, Lingjie Li, Wenliang Gao*, Rihong Cong, Tao Yang*, Octahedral-based redox molecular sieve M-PKU-1: isomorphous metal-substitution, catalytic oxidation of sec-alcohol and related catalytic mechanism, J. Catal. 2017, 352, 130-141

2.    Weilu Wang, Siyu Zhang, Shixiang Hu, Duo Wang, Wenliang Gao*, Rihong Cong, Tao Yang*, Octahedron-based redox molecular sieves M-PKU-1 (M = Cr, Fe): A novel dual-centered solid acid catalyst for heterogeneously catalyzed Strecker reaction, Applied Catal. A: 542 (2017) 240-251

3.    Fenhua Zhang, Weilu Wang, Shixiang Hu, Xiaotong Ma, Wenliang Gao*, Rihong Cong and Tao Yang*, “A nanosized aluminoborate (PKU-5) with Cr-centered octahedral framework: solid-phase synthesis, characterizations and catalytic ammoximation of cyclohexanone to cyclohexanone azine”, Applied Catal. A: 531 (2017) 60–68.

4.    G. J. Wang, W. L. Wang, F. H. Zhang, W. L. Gao,* R. H. Cong, T. Yang,* “Octahedron-based gallium borates (Ga-PKU-1) with open-framework: acidity, catalytic dehydration and structure-activity relationship”, Catal. Sci. Technol., 2016, 6, 5992–6001.

5.    W. L. Wang, Y. Wang, B. Wu, R. H. Cong, W. L. Gao,* B. Qin,* T. Yang, “Octahedra-based Molecular Sieve Alunimoborate (PKU-1) as Solid Acid for Heterogeneously Catalyzed Strecker Reaction” Catal. Commun. 2015, 58, 174-178.

6.    J. Xiang, Q. Q. Li, G. J. Wang, J. Ju, R. H. Cong, W. Yin, W. L. Gao,* T. Yang,* “(Al1-xCrx)4B6O15 (0.08 ≤ x ≤ 0.14): Metal Borates Catalyze the Dehydration of Methanol into Dimethyl Ether” Mater. Res. Bull. 2015, 65, 279-286.

7.    R. Wang, M. F. Yue, R. H. Cong, W. L. Gao,* T. Yang,* “Photocatalytic reduction of nitrate over chalcopyrite CuFe0.7Cr0.3S2 with high N2 selectivity”, J. Alloy Compd. 2015, 651, 731-736.

8.    X. Huang, Y. Jing, J. Yang, J. Ju, R. H. Cong, W. L. Gao,* T. Yang,* “Flower-like Nanostructure MNb2O6 (M = Mn, Zn) with High Surface Area: Hydrothermal Synthesis and Enhanced Photocatalytic Performance” Mater. Res. Bull. 2014, 51, 271-276.

9.    J. Yang, M. F. Yue, J. Ju, R. H. Cong, W. L. Gao,* T. Yang,* “Co-molten solvothermal method for synthesizing chalcopyrite CuFe1-xCrxS2 (x ≤ 0.4): high photocatalytic activity for nitrate ions reduction” Dalton Trans. 2014, 43, 15385-15390.

10. W. L. Gao, Y. Jing, J. Yang, Z. Y. Zhou, D. F. Yang, J. L. Sun, J. H. Lin, R. H. Cong,* T. Yang,* “Open-framework Gallium Borate with Boric and Metaboric Acid Molecules inside Structural Channels Showing Photocatalysis to Water Splitting” Inorg. Chem. 2014, 53, 2346-2366

11. D. F. Yang, Y. Jing, Y. Zhang, X. M. Liu, Z. S. Lin, R. H. Cong,* W. L. Gao,* T. Yang, “CdB10O14(OH)4•H2O with an unprecedented decaborate fundamental building block”, Mater. Res. Bull. 2013, 48, 270-276.

12. D. F. Yang, R. H. Cong, W. L. Gao,* T. Yang,* “Boric acid flux synthesis, structure and magnetic property of MB12O14(OH)10 (M = Mn, Fe, Zn)”, J. Solid State Chem. 2013, 201, 29-34.

13. W. L. Gao, Y. X. Wang, G. B. Li, F. H. Liao, L. P. You, J. H. Lin*, Synthesis and Structure of an Aluminum Borate Chloride Consisting of 12-Membered Borate Rings and Aluminate Clusters, Inorg. Chem. 2008, 47, 7080–7082

14. W. L. Gao, T. Yang, Y. X. Wang, G. B. Li, Fuhui Liao, J. H. Lin,* Synthesis, characterization and catalytic performance of Cr-incorporated Aluminoborate octahedral molecular sieves, J. Phys. Chem. B, 2005, 109, 22775-22779

15. W. L. Gao, R. C. Jin, J. X. Chen, H. S. Zeng, F. X. Zhang, N. J. Guan,* Titania-Supported Bimetallic Catalysts for Photocatalytic Reduction of Nitrate, Catal. Today, 2004, 90, 331-336

16. W. L. Gao, X. X. Guan, J. X. Chen, R. C. Jin, F. X. Zhang, N. J. Guan,* Catalytic reduction of nitrite ions in drinking water over Pd-Cu/TiO2 bimetallic catalyst, Cataly. Today, 2004, 93-95 C, 331-337

17. W. L. Gao, N. J. Guan,* J. X. Chen, H. S. Zeng, Z. G. Liu, Titania Supported Pd-Cu Bimetallic Catalyst for the Reduction of Nitrate in Drinking Water, Appl. Catal. B: Environ., 2003, 46, 341-351

18. W. L. Gao, R. C. Jin, J. X. Chen, F. X. Zhang, Z. G. Liu, N. J. Guan,* Titania Supported Pd-Cu Bimetallic Catalyst for the Reduction of Nitrite in Drinking Water, Catal. Lett., 2003, 91, 25-30

2)其他文章

19. H. Chen, J. Ju, Q. P. Meng, J. Su, C. Lin, Z. Y. Zhou, G. B. Li, W. L. Wang, W. L. Gao, C. M. Zeng, C. Tang, J. H. Lin,* T. Yang,* J. L. Sun,* “PKU-3: An HCl-inclusive aluminoborate for Strecker reaction solved by combining RED and PXRD”, J. Am. Chem. Soc. 2015, 137, 7047-7050.

20. J. Yang, H. Fu, D. F. Yang, W. L. Gao, R. H. Cong,* T. Yang,* “ZnGa2-xInxS4 (0 ≤ x ≤ 0.4) and Zn1-2y(CuGa)yGa1.7In0.3S4 (0.1 ≤ y ≤ 0.2): Optimize visible light photocatalytic H2 evolution by fine modulation of band structures”, Inorg. Chem. 2015, 54, 2467-2473.

21. G. J. Wang, J. Yan, J. Ju, D. F. Yang, J. Yang, W. L. Gao, R. H. Cong,* T. Yang,* “Ga4B2O9: An Efficient Borate Photocatalyst for Overall Water Splitting without Co-catalyst”, Inorg. Chem. 2015, 54, 2945-2949.

22. B. Ma, R. H. Cong, W. L. Gao, T. Yang,* “Photocatalytic overall water splitting over an open-framework gallium borate loaded with various cocatalysts”, Catal. Commun. 2015, 71, 17-20.

23. Q. Q. Li, C. Lin, Z. Y. Zhou, J. Ju, W. L. Gao, R. H. Cong,* T. Yang,*Systematic Study of Cr3+ Substitution into Octahedra-based Microporous AluminoboratesInorg. Chem. 2014, 53, 5600-5608.

24. F. X. Zhang, R. C. Jin, J. X. Chen, W. L. Gao, N. J. Guan,* High photocatalytic activity and selectivity for nitrogen in nitrate reduction on Ag/TiO2 catalyst with fine silver clusters, J. Catal., 2005, 232, 424-431

25. R. C. Jin, W. L. Gao, J. X. Chen, H. S. Zeng, F. X. Zhang, N. J. Guan,* Photocatalytic Reduction of Nitrate Ion in Drinking Water by Using Metal Loaded on MgTiO3-TiO2 Composite Semiconductors Catalyst Systems, J. Photochem, & Photobiol, A: Chem, 2004, 192, 585-590

26. F. X. Zhang, J. X. Chen, X. Zhang, W. L. Gao, R. C. Jin, N. J. Guan,* Y. Z. Li, Synthesis of Titania-Supported Platinum Catalyst: The Effect of pH on Morphology Control and Valence State during Photodeposition, Langmuir, 2004, 20, 9329-9334

五、科研项目及奖励

1.    重庆市科技计划项目基础与前沿研究计划:《基于八面体骨架的微孔硼酸盐的合成、金属掺杂及催化性能》;cstc2014jcyjA500362014-2017,主持;

2.    重庆市科技攻关重大项目:《万吨级蛋氨酸合成关键技术研究与产业化》;CSTC2010aa4056, 2011-2012, 主持;

3.    中央高校基本科研业务费面上项目:《八面体骨架氧化还原分子筛的合成、结构及其催化性能》; 2010-2011, 主持;

4.    重庆市自然科学基金:《新型稀土多硼酸盐的合成、结构和光学性能的研究》,CSTC2007BB4151, 2007-2009, 主持;

5.    中国博士后科学基金:《八面体硼铝分子筛的合成、结构和催化性能研究》,2005-2006, 主持

6.    国家自然科学基金面上项目,21671028,《利用固体化学方法研究可见光全分解水催化材料与高性能热电半导体》,2017/01-2020/12,参加;

7.    国家自然科学基金面上项目,21171178,《含铋的复杂氧化物体系中新型多铁性材料的开发研究,2012/01-2015/12》,50万元,结题,参加;

8.    国家自然科学基金项目重大研究计划培育项目:《PKU系列微孔硼铝酸盐的合成、晶体结构、金属掺杂与催化性质研究》;91222106, 2013-2015, 参研;

9.    2013年重庆市教学成果二等奖:《现代基础化学系列课程体系的改革与实践》;

10. 2005年天津市自然科学二等奖:《纳米新催化材料的制备及其在环保中的应用基础研究》。